ISSN 1009-6248CN 61-1149/P Bimonthly

Supervisor：China Geological Survey

Sponsored by：XI'an Center of China Geological Survey
Geological Society of China

    • The Core Journals of China
    • The Key Magazine of China Technology
    • CSCD Included Journals
    • Scopus Included Journals
Advance Search
SUN Ningyue, LI Guowu, SHEN Junfeng, et al. Relationship between Fine Structure and Cell Parameters of Pyrite and Their Typomorphic Significance[J]. Northwestern Geology, 2022, 55(4): 333-342. DOI: 10.19751/j.cnki.61-1149/p.2022.04.027
Citation: SUN Ningyue, LI Guowu, SHEN Junfeng, et al. Relationship between Fine Structure and Cell Parameters of Pyrite and Their Typomorphic Significance[J]. Northwestern Geology, 2022, 55(4): 333-342. DOI: 10.19751/j.cnki.61-1149/p.2022.04.027
shu

Relationship between Fine Structure and Cell Parameters of Pyrite and Their Typomorphic Significance

  • 1. Laboratory of Crystal Structure, China University of Geosciences(Beijing), Beijing 100083, China;

  • 2. School of Earth Sciences and Resources, China University of Geosciences(Beijing), Beijing 100083, China;

  • 3. Cores and Samples Center of Natural Resource, China Geological Survey, Yanjiao 065201, Hebei, China;

  • 4. School of Materials Science and Technology, China University of Geosciences(Beijing), Beijing 100083, China

More Information
  • Received Date: March 11, 2022
  • Revised Date: August 07, 2022
  • Available Online: January 09, 2023
    Graphical Abstract
    • Abstract
  • Pyrite is the main gold bearing mineral in endogenetic gold deposits, and its typomorphic characteristics have important implications for gold mineralization. At present, the typomorphic characteristics of pyrite are mainly focused on the morphology and physicochemical properties, while the microstructure characteristics of pyrite, such as unit cell parameters, bond length & bond angle, are less studied. Moreover, the existing studies mainly focus on the influence of composition on cell parameters. Few people have analyzed the relationship between fine structure of pyrite characterized by bond length & bond angle and cell parameters.The experimental samples were collected from Sanshandao Gold Deposit in Laizhou, Shandong Province. The crystal structure data of pyrite were collected by single crystal X-ray diffraction, and the fine structure data were obtained by analytical software. The influence of bond length&bond angle on the lattice parameters of pyrite was analyzed by spatial geometric relationship and partial derivative. It was found that the lattice parameters of pyrite were mainly affected by the internal coordination octahedron.The effect of the size of the ligands is less affected by the gap between the ligands. The size of the octahedron is closely related to the length of the Fe-S bond in the octahedron, and the size of the space between the coordination bodies can be characterized by the Fe-S-Fe bond angle or the S-S bond length.The reason for the change of Fe-S bond length is related to the isomorphism of Co, Ni, Cu replacing Fe and As replacing S. This provides a theoretical basis for the change of unit cell parameters, and is of great significance for guiding gold production with the typomorphic characteristics of unit cell parameters.
    • FullText(HTML)
    • References (49)
  • 陈随,韩世礼.埃塞俄比亚施瑞地区VMS型铜金矿床黄铁矿成因及矿物学特征研究[J].矿产勘查,2020,11(07):1422-1427.
    CHEN Sui,HAN Shili.Genesis and Mineralogy of Pyrite in The VMS Copper—Gold Deposit in Shirui Area, Ethiopia[J].Mineral Exploration,2020,11(07):1422-1427.
    陈玉民,张华锋,张聪颖,等.黄铁矿标型特征对胶东三山岛金矿深部矿化的启示[J].黄金科学技术,2019,27(5):11.
    CHEN Yumin,ZHANG Huafeng,ZHANG Congying,et al.Pyrite Typomorphic Characteristics: Implication for Deep Gold Mineratization in the Sanshandao Gold Deposit, Jiaodong Peninsula[J].Gold Science and Technology,2019,27(5):11.
    范裕,袁峰,张千明,等.安徽香泉独立铊矿床中含铊黄铁矿的X衍射研究及其矿物学意义[J].合肥工业大学学报(自然科学版),2008,31(7):995-999.
    FAN Yu,YUAN Feng,ZHANG Qianming,et al.XRD Analysis and Mineralogical Significance of Tl-bearing Pyrite in Xiangquan Independent Thallium Deposit[J].Journal of Hefei University of Technology,2008,31(7):995-999.
    高建伟,申俊峰,李国武，等.胶东三山岛北部海域金矿黄铁矿晶胞参数与热电性特征[J].矿物岩石地球化学通报,2020,39(06):1205-1214.
    GAO Jianwei,SHEN Junfeng,LI Guowu,et al.Characteristics of Cell Parameters and Thermoelectricity of the Pyrite in the Sanshandao North Off Shore Gold Deposit, Shandong Province, China[J].Bulletin of Mineralogy, Petrology and Geochemistry,2020,39(06):1205-1214.
    高永伟,王志华,黎卫亮，等.热液型金矿床中的黄铁矿矿物学研究综述[J].西北地质,2019,52(03):58-69.
    GAO Yongwei,WANG Zhihua,LI Weiliang,et al.A Review of Pyrite Mineralogy Research in Hydrothermal Gold Deposits[J],Northwestern Geology,2019,52(03):58-69.
    林木森,黄火亮.福建邵武金坑金矿床黄铁矿特征及其对成矿的指示意义[J].矿业工程,2019,17(01):9-12.
    LIN Musen,HUANG Huoliang.Features of Pyrite of Gold Deposit of Shaowu Gold Pit in Fujian and Its Indication Significance for Mineralization of the Deposit[J].Mining Engineering,2019,17(01):9-12.
    林祖苇,赵新福,熊乐,等.胶东三山岛金矿床黄铁矿原位微区微量元素特征及对矿床成因的指示[J].地球科学进展,2019,34(04):399-413.
    LIN Zuwei, ZHAO Xinfu, XIONG Le, et al.In-situ Trace Element Analysis Characteristics of Pyrite in Sanshandao Gold Deposit in Jiaodong Peninsula[J].Implications for ore Genesis Advances in Earth Science,2019,34(04):399-413.
    李小宁,王翠芝,包宝同，等.福建紫金山金铜矿黄铁矿成因矿物学特征研究[J].有色金属(矿山部分),2015,67(02):36-41.
    LI Xiaoning,WANG Cuizhi,BAO Baotong,et al.Study on Genetic Mineralogical of Pyrite from Zijinshan Au-Cu Deposit, Fujian Province Nonferrous[J].Metals(Mine Section),2015,67(02):36-41.
    李逸凡,李洪奎,汤启云，等.山东旧店金矿黄铁矿标型特征及其地质意义[J].黄金科学技术,2015,23(02):45-50.
    LI Yifan,LI Hongkui,TANG Qiyun,et al.Typomorphic Characteristics and Geological Significance of Pyrite in Jiudian Gold Deposit, Shandong Province[J].Gold Science and Technology,2015,23(02):45-50.
    茆诗松,王静龙,濮晓龙.高等数理统计[M].北京:高等教育出版社, 2006.
    MAO Shisong,WANG Jinglong,PU Xiaolong.Advanced Mathematical Statistics[M].Beijing:Higher Education Press,2006.
    孟繁聪,孙岱生,李胜荣，等.山东烟台南张家金矿黄铁矿的标型特征[J]. 现代地质,2001,15(2):231-237.
    MENG Fancong,SUN Daisheng,LI Shengrong,et al.Typomorphic Characteristic of Pyrite in the Nanzhangjia Gold Mineral Deposit, Shandong Province[J].Geoscience,2001,15(2):231-237.
    申俊峰,李胜荣,马广钢,等.玲珑金矿黄铁矿标型特征及其大纵深变化规律与找矿意义[J]. 地学前缘,2013,20(03):55-75.
    SHEN Junfeng,LI Shengrong,MA Guanggang,et al.Typomorphic Characteristics of Pyrite from the Linglong Gold Deposit: Its Vertical Variation and Prospecting Significance[J].Earth Science Frontiers,2013,20(03):55-75.
    陶诗龙,赖健清,张建东,等.广西龙头山金矿床黄铁矿标型特征及其地质意义[J].地质找矿论丛,2017,32(01):33-41.
    TAO Shilong,LAI Jianqing,ZHANG Jiandong,et al.Typomorphic Features of Pyrites from the Longtoushan Gold Deposit, Guangxi Province and the Geological Significance[J].Contributions to Geology and Mineral Resources Research,2017,32(01):33-41.
    吴晋超,申俊峰,申玉科，等.胶东黑岚沟金矿田黄铁矿热电性研究及深部成矿预测[J].西北地质,2021,54(02):111-125.
    WU Jinchao,SHEN Junfeng,SHEN Yuke,et al.The Rmoelectricity Property and Deep Metallogenic Forecast of Pyrite in Heilangou, Gold Field of Jiaodong, Shandong Province[J].Northwestern Geology,2021,54(02):111-125.
    魏明秀.黄铁矿晶胞参数公式的研究[J].科学通报,1980,(17):816.
    WEI Mingxiu.Study on the Formula of Unit Cell Parameters of Pyrite[J].Chinese Science Bulletin,1980,(17):816.
    王学明.略论黄铁矿晶胞参数变异原因及研究意义[J].黄金科技动态, 1991,(08):30-33.
    WANG Xueming.A Brief Discussion on the Cause of Variation of Unit Cell Parameters of Pyrite and Its Research Significance[J].Gold Science and Technology,1991,(08):30-33.
    张龙,李胜荣,宋英昕,等.胶东西北部望儿山金矿床黄铁矿标型特征及找矿意义[J].岩石矿物学杂志,2020,39(02):159-171.
    ZHANG Long,LI Shengrong,SHONG Yingxin,et al.Typomorphic Characteristics of Pyrite in the Wangershan Gold Deposit, Northwest Jiaodong, and Its Prospecting Significance[J].Acta Petrologica et Mineralogica,2020,39(02):159-171.
    张维睿,韦承谦.伴金黄铁矿(Pyrite)结构的研究[J].北京大学学报:自然科学版,1991, 27(02):184-191.
    ZHANG Weirui,WEI Chengqian.Study on the Crystal Structure of the Pyrite with Au[J].Alta Scientiarum Naturalium Universitatis Pekinensis,1991,27(02):184-191.
    周学武,李胜荣,鲁力,等. 辽宁丹东五龙矿区石英脉型金矿床的黄铁矿标型特征研究[J]. 现代地质,2005,19(2):77-84.
    ZHOU Xuewu,LI Shengrong,LU Li,et al.Study of Pyrite Typomorphic Characteristics of Wulong Quartz-Vein-Type Gold Deposit in Dandong, Liaoning Province, China[J].Geoscience,2005,19(2):77-84.
    Arehart G B,Eldridge C S,Chryssoulis S L,et al.Ion Microprobe Determination of Sulfur Isotope Variations in Iron Sulfides from the Post/Betze Sediment-hosted Disseminated Gold Deposit, Nevada, USA[J].Geochimica et Cosmochimica Acta,1993,57(7):1505-1519.
    Bindi L,Moelo Y,Leone P,et al.Stoichiometric Arsenopyrite, FeAsS, from La Roche-Balue Quarry, Loire-Atlantique, France: Crystal Structure and Mossbauer Study[J].Canadian Mineralogist, 2012,50(2):471-479.
    Bragg W L.The Analysis of Crystals by the X-Ray Spectrometer[M].Proceedings of the Royal Society of London,1914,89(613):468-489.
    Dodony I,Posfal M,Buseck P R.Structural Relationship Between Pyrite and Marcasite[J]. American Mineralogist,1996,81(1-2):119-125.
    King H E,Prewitt T.Structure and Symmetry of CuS,(pyrite structure)[J].American Mineralogist, 1979,64:1265-1271.
    Mosselmans J,Pattrick R,Laan G,et al.X-ray Absorption Near-edge Spectra of Transition Metal Disulfides FeS2(pyrite and marcasite), CoS2, NiS2 and CuS2, and Their Isomorphs FeAsS and CoAsS[J].Physics & Chemistry of Minerals,1995,22(5):311-317.
    Nickel E H.Structural Stability of Minerals with the Pyrite, Marcasite, Arsenopyrite and Lollingite Structures[J].The Canadian Mineralogist,1968,9(3):311-321.
    Nowack E,Schwarzenbach D,Hahn T.Electron Density in Compounds with Pyrite Structure: FeS2, CoS2, NiS2[J].Twelth European Crystallographic Meeting,1989,186(3):213-215.
    Nowack E,Schwarzenbach D,Hahn T.Charge Densities in CoS2 and NiS2(pyrite structure)[J].Acta Crystallographica,1991,47(5):650-659.
    Simon G.Geochemistry And Textures of Gold-Bearing Arsenian Pyrite, Twin Creeks Carlintype Gold Deposit, Nevada. Implications for Gold Deposition[J].Economic Geology,1999,94(3):405-421.
    Stevens E D,Delucia M L,Coppens P.Experimental Observation of the Effect of Crystal Field Splitting on the Electron Density Distribution of Iron Pyrite[J].Cheminform,1980, 11(4):813-820.
    • Related Articles

  • Related Articles

    LIU Xiangdong, HUANG Honglin, LIU Xingyu, SUN Jianwei, JIA Xu, ZHAO Xingzhi, ZHANG Xuhuang, CHENG Xianda, SUN Yake. 2025: Study on the Starting Characteristics of Mine Debris Flow Based on Flume Test: Take the Kangshan Gold Mining Area in Luanchuan County as an example. Northwestern Geology, 58(1): 300-314. DOI: 10.12401/j.nwg.2023194
    LIU Xingyu, ZHU Lifeng, SUN Jianwei, JIA Xu, LIU Xiangdong, HUANG Honglin, CHENG Xianda, SUN Yake, HU Chaojin, ZHANG Xiaolong. 2024: Precise Calculation for Characteristic Parameters of Valley-type Debris Flow Using a Methed of Recursive Equivalent Area Substitution. Northwestern Geology, 57(3): 272-284. DOI: 10.12401/j.nwg.2023166
    ZHUANG Tianming, LI Xiaofei, WANG Xinyan. 2022: Geological Characteristics, Ore-controlling Factors and Prospecting Criteria of Lateritic Gold Deposits. Northwestern Geology, 55(2): 176-184. DOI: 10.19751/j.cnki.61-1149/p.2022.02.015
    LIU Kunfeng, FENG Changrong, QI Xiaopeng, XIE Jin, ZHAI Liming, QU Xiaoxiang, LEI Hao. 2020: Geological Characteristics and Prospecting Indicator of Wuheshalu Sandstone Copper Deposit in Wuqia County, Xinjiang. Northwestern Geology, 53(3): 113-126. DOI: 10.19751/j.cnki.61-1149/p.2020.03.010
    LIU Chao, WANG Yalei, ZHANG Zhaowei, LIU Yuegao, HAN Yixiao, DONG Yibo, LENG Xin. 2020: The Genetic Significance of Pentlandite and Pyrrhotite and the Characteristics of Cobalt Occurrence in Xiarihamu Cobalt-Nickel Deposit of Eastern Kunlun. Northwestern Geology, 53(2): 183-199. DOI: 10.19751/j.cnki.61-1149/p.2020.02.011
    HUANG Jianguo, YANG Jian, CUI Chunlong, LI Wenjie, HOU Lanjie. 2017: Geological Characteristics of Devonian Sandstonetype Copper Deposit in Kusilafu Area,Southwestern Tarim Basin:Evidence from Saigeziganleke Copper deposit. Northwestern Geology, 50(2): 136-141.
    LIU Shengyou. 2015: Geological Characteristics and Metallogenic Model of Dewulu Skarn-type Copper Deposits in West Qinling, Gansu Province. Northwestern Geology, 48(2): 176-185.
    FENG Zhang-sheng, ZHANG Xia-tao, JIAO Jin-rong, WANG Zhao-quan, WANG Qiang, Wang Ju-chan. 2013: Characteristics and Prospecting Direction of Granitic Pegmatite-Type Uranium in Danfeng Area, Shaanxi Province. Northwestern Geology, 46(2): 159-166.
    LI Dong-Sheng, GU Feng-Bao, ZHANG Hai-Lan, SU Sheng-Shun, ZHONG Liang-Yan, LIU Guang-Lian. 2012: Geologic Characteristics of the Kaerqueka Porphyry Copper Deposit in Qinghai Province and Its Prospecting Significance. Northwestern Geology, 45(1): 174-183.
    LIU Bo-chong, LI Jin-chun, MA Yun-hai. 2005: Characteristic of silstone copper ore in Tianlu copper deposit. Northwestern Geology, 38(3): 41-47.

  • Cited by

    Periodical cited type(5)

    1. 杨科，樊自春，杨晓飞，李小宇，梁金龙，李军. 西秦岭阳山金矿床黄铁矿标型特征及成矿意义. 甘肃地质. 2024(03): 7-15 .
    2. 潘雪玲，程伟，侯慧. 煤系黄铁矿的矿物学特征研究. 有色金属(选矿部分). 2024(11): 21-32 .
    3. 童丽嵘，杨喜云，吴玉楼，朱静，陈莹丽. 硫铁矿还原净化含铁渣酸浸液制备硫酸亚铁. 中南大学学报(自然科学版). 2024(11): 4283-4294 .
    4. 葛战林，顾雪祥，章永梅，郑艳荣，刘明，郝迪，王元伟. 南秦岭柞水-山阳矿集区金盆梁金矿床载金硫化物矿物学特征及成矿指示. 西北地质. 2023(05): 278-293 . 本站查看
    5. 冯李强，顾雪祥，章永梅，沈睿文，张英帅，王鹏飞，王大伟. 山东蓬莱石家金矿床载金黄铁矿热电性、晶胞参数及其找矿意义. 矿床地质. 2023(05): 877-891 .

    Other cited types(3)

Catalog

    Get Citation
    PDF
    XML
    Article views (46) PDF downloads (18) Cited by(8)
    Turn off MathJax
    Article Contents
    Abstract
    References
    Related Articles

    Address：No. 555 Cangtai West Road, Chang'an District, Xi'an 710119, ChinaPostCode：710119

    Tel：+86-29-89238533E-mail： xbdzbjb@163.com

    Copyright : Editorial Office of Northwestern Geology陕ICP备13001446号

    Supported by: Beijing Renhe Information Technology Co., Ltd.  Baidu Analytics

    /

    DownLoad:  Full-Size Img  PowerPoint
    Return
    Return