Petrochemical Characteristics and Geological Significance of Middle Triassic Granodiorites from Lalinggaoli River Area in Qinghai
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Graphical Abstract
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Abstract
The intermediate-acid intrusive rocks are intensively developed in Lalinggaili river area, Qinghai, which is a rock combination of diorite, quartz diorite, tonalite, granodiorite and monzonitic granite with fine grain. Through the analysis of the granite diorite, the results show that SiO2, Al2O3, K2O, Na2O, CaO values and σ indexes range from 67.01% to 70.92%, from 14.13% to 15.44%, from 3.18% to 4.03%, from 2.78% to 3.74%, from 2.6% to 4.15% and from 1.6 to1.92, respectively. The geochemical characteristics suggest that these granites belong to high potassium calc-alkaline series. REE characteristics show that, the ∑REE values are 106.48×10-6~145.87×10-6, LREE/HREE ratios vary from 8.967 to15.136, and the δEu value range from 0.504 to 0.83. The spider patterns are the right-incline, with low Eu positive abnormality and LREE-rich smooth curves. The trace element characteristics indicate that they are enriched in LILE (Rb, Ce, Th, LREE) and depleted in HFSE (Nb, P, Ti, Sr, Ba). The LA-ICP-MS zircon U-Pb age of granodiorite is (234.9±1.3)Ma, which was formed in Middle Triassic epoch. By constructing environmental analysis, it is believed that the granodiorite from Lalinggaili river area is came from the crust-mantle mixed source, which was served as the product of crustal melting during intracontinental subduction stage, with the participation of mantle materials.
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