ISSN 1009-6248CN
61-1149/P Bimonthly
Supervisor：China Geological Survey
Sponsored by：XI'an Center of China Geological Survey
Geological Society of China
Supervisor：China Geological Survey
Sponsored by：XI'an Center of China Geological Survey
Geological Society of China
| Citation: |
XU Youning, CHEN Huaqing, KE Hailing, et al. Analysis of White Pollution of River Aluminum in Stone CoalMining Area in Haoping River Basin and Its Causes[J]. Northwestern Geology, 2023, 56(4): 128-140. DOI: 10.12401/j.nwg.2023141
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Acid mine drainage and its associated heavy metal pollution are the most important mine pollution problems in pyrite−bearing mining areas and the most difficult to comprehensively treat. In order to find out the white pollution and causes of aluminum mining rivers from abandoned stone coal mines in the Haoping river basin, satellite remote sensing interpretation, non−fixed−wing UAV aerial survey, sample collection and analysis, and dynamic monitoring of water quality in major river sections have been carried out since 2021. The results show that, ①white pollution of aluminum is common in rivers in the study area, and three patterns can be seen: the two channels are mixed with river water with different pH degrees to form white water belts; after the natural fall of the river water, white pollutants are formed on the rock surface of the riverbed; river water naturally evolves to form acidic water, acidic sulfur water, and acidic white water. ②Aluminum ion pollution in river water was widespread and seriously exceeded the standard, the average content of Al ions in 216 river waters was 8.6 mg/l, the sample exceeded the standard rate by 65.8%, and the average excess rate of Al ions in the three river waters of 19 river sections was 90.48%. ③ The aluminum in the river comes from the result of the acid water dissolution of feldspar in the stone coal mine and its surrounding rock, and the flowing water at the bottom of the waste residue pile is the main source of pollution of the river aluminum. ④ Aluminum ions in river water have a significant negative correlation with pH, and the greater the acidity of river water, the higher the content of aluminum ions in river water; after the formation of white amorphous gels in river water, the content of aluminum ions in river water decreased significantly. The increase in the pH of river water is the main factor in the formation of white pollutants in rivers. The white pollutants of aluminum in river water have amorphous characteristics, complex chemical composition, and are complex compounds composed of sulfate, hydroxide and aluminum. The white amorphous gel of aluminum has the ability to adsorb heavy metal ions in river water. The research results can have important theoretical and practical application value for the pollution prevention and control of aluminum in the research area.
|
陈谦, 杨晓松, 吴义千等. 有色金属矿山酸性废水成因及系统控制技术[J]. 矿冶, 2005, 14(04): 71-74 doi: 10.3969/j.issn.1005-7854.2005.04.020
CHEN Qian, YANG Xiaosong, WU Yiqian, et al. Formation of waste water from nonferrous metal mine and its systematical control technique[J]. Mining and Metallurgy, 2005, 14(04): 71-74. doi: 10.3969/j.issn.1005-7854.2005.04.020
|
|
陈华清, 张天亮, 龚慧山, 等.矿山酸性水中铝相次生矿物及环境学意义的研究进展. 西北地质, 2023, 56(4): 1-11. doi: 10.3969/j.issn.1001-6996.2010.01.001
CHEN Huaqing, ZHANG Tianliang, GONG Huishan, et al. Research Progress of Aluminum−Phase Secondary Minerals and Their Environmental Significance in Acid Mine Water. Northwestern Geology, 2023, 56(4): 1-11. doi: 10.3969/j.issn.1001-6996.2010.01.001
|
|
陈西民, 马合川, 魏东等. 安康石煤资源特征及勘查开发建议[J]. 陕西地质, 2010, 28(01): 1-5+81 doi: 10.3969/j.issn.1001-6996.2010.01.001
CHEN Ximin, MA Hechuan, WEI Dong, et al. An kang stone coal resource characteristics and exploration and development suggestions[J]. Geology of Shananxi, 2010, 28(01): 1-5+81. doi: 10.3969/j.issn.1001-6996.2010.01.001
|
|
崔炜, 张佳伟, 苏文让, 等. 石煤采矿区水流域重金属污染治理实践[J]. 《环境工程》编委会, 工业建筑杂志社有限公司. 《环境工程》2019年全国学术年会论文集[C]. 《工业建筑》杂志社有限公司, 2019: 6 doi: 10.13779/j.cnki.issn1001-0076.2021.02.022
CUI Wei, ZHANG Jiawei, SU Wenrang, et al. Prractice of Heavy Metal Pollution Control in Water Basin of Stone Coal Mining Area[J]. Editorial Board of Environmental Engineering, Industrial Architecture Magazine. Proceedings of the 2019 National Annual Conference of Environmental Engineering[C]. Industrial Construction Magazine Limited, 2019: 6. doi: 10.13779/j.cnki.issn1001-0076.2021.02.022
|
|
崔雅红, 崔炜, 孟庆俊等. 陕西蒿坪石煤矿区重金属污染及生态风险评价[J]. 矿产保护与利用, 2021, 41(02): 157-162 doi: 10.13779/j.cnki.issn1001-0076.2021.02.022
CUI Yahong, CUI Wei, MENG Qingjun, et al. Heavy Metal Pollution and Ecological Risk Assessment in Haoping Stone Coal Mine Area of Shaanxi Province[J]. Conservation and Utilization of MineralResources, 2021, 41(02): 157-162. doi: 10.13779/j.cnki.issn1001-0076.2021.02.022
|
|
大连理工大学无机化学教研室编. 无机化学第四版[M]. 北京: 高等教育出版社, 2001 doi: 10.3969/j.issn.1005-9954.2018.03.002
Department of Inorganic Chemistry, Dalian University of Technology. The fourth edition of inorganic chemistry[M]. Beijing: Higher Education Press, 2001. doi: 10.3969/j.issn.1005-9954.2018.03.002
|
|
杜蕾, 朱晓丽, 安毅夫等. 石煤尾矿区土壤重金属污染风险评价[J]. 化学工程, 2018, 46(03): 6-9+15 doi: 10.3969/j.issn.1005-9954.2018.03.002
DU Lei, ZHU Xiaoli, AN Yifu, et al. Potential ecological risk assessment of soil heavy metalsin a stone-like coal tailing using TCLP and Hakanson method[J]. Chemical Engineering(China), 2018, 46(03): 6-9+15. doi: 10.3969/j.issn.1005-9954.2018.03.002
|
|
贾晓丹, 王晖, 徐友宁. 某钼矿集中开采区尾矿库排水重金属环境风险等级及其贡献率分析. 西北地质, 2023, 56(4): 152−161.
JIA Xiaodan, WANG Hui, XU Youning. Analysis of Heavy Metal Environmental Risk Level and Contribution Rate of Tailings Storerooms of A Molybdenum Mine. Northwestern Geology, 2023, 56(4): 152-161.
|
|
贾志刚, 吕婷婷. 安康市双龙一带斑鸠关组地质特征及其含石煤性分析[J]. 煤, 2014, 23(02): 52-53+76.
LI Meirong, SONG Laidi, YU Haipeng, et al. Influence of pH value on feldspar dissolution and pore-increasing effect[J]. Journal of China University of Petroleum(Edition of Natural Science), 2021, 45(05): 33-41.
|
|
栾兆坤. 水中铝的形态及其形态研究方法[J]. 环境化学, 1987(01): 46-56 doi: 10.3969/j.issn.1007-2802.2001.02.007
LUAN Zhaokun. The speciation and speciation study of aluminum in water[J]. Environmental Chemistry, 1987(01): 46-56. doi: 10.3969/j.issn.1007-2802.2001.02.007
|
|
李美蓉, 宋来弟, 于海鹏等. 酸碱度对长石溶蚀及增孔效应的影响[J]. 中国石油大学学报(自然科学版), 2021, 45(05): 33-41 doi: 10.3321/j.issn:1001-8166.2008.05.010
LI Meirong, SONG Laidi, YU Haipeng, et al. Influence of pH value on feldspar dissolution and pore-increasing effect[J]. Journal of China University of Petroleum(Edition of Natural Science), 2021, 45(05): 33-41. doi: 10.3321/j.issn:1001-8166.2008.05.010
|
|
罗孝俊, 杨卫东, 李荣西等. pH值对长石溶解度及次生孔隙发育的影响[J]. 矿物岩石地球化学通报, 2001, 20(02): 103-107 doi: 10.3969/j.issn.1007-2802.2001.02.007
LUO Xiaojun, YANG Weidong, LI Rong xi, et al. Effects of pH on the Solubility of the Feldspar and the Development of Secondary Porosity[J]. Bulletin of Mineralogy Petrology and Geochemistry, 2001, 20(02): 103-107. doi: 10.3969/j.issn.1007-2802.2001.02.007
|
|
倪师军, 李珊, 李泽琴等. 矿山酸性废水的环境影响及防治研究进展[J]. 地球科学进展, 2008, 23(05): 501-508 doi: 10.3321/j.issn:1001-8166.2008.05.010
NI Shijun, LI Shan, LI Zeqin, et al. Progress in the Research of Acid Mine Drainage Impact and Remediation[J]. Advances In Earth Science, 2008, 23(05): 501-508. doi: 10.3321/j.issn:1001-8166.2008.05.010
|
|
庞洁. 铝对人体的毒性及相关食品安全问题研究进展[J]. 内科, 2011, 6(05): 470-473. doi: 10.3969/j.issn.1673-7768.2011.05.038
WANG Yinchuan, LI Zhaokun, ZHAI Zifeng, et al. Benxi Formation Bauxite Mineralization Condition and Rule in Shanxi Province[J]. Northwestern Geology, 2011, 44(4): 82-88. doi: 10.3969/j.issn.1673-7768.2011.05.038
|
|
王晓勇, 徐友宁, 赵振宏等. 石煤矿区酸性废水稳定同位素特征及地质意义[J]. 西北地质, 2023, 1-7
WANG Xiaoyong, XU Youning, ZHAO Zhenhong, et al. Stable Isotope Characteristics and Geological Significance of Acid Wastewater in a Stone Coal Mining Area[J]. Northwestern Geology, 2023, 1-7.
|
|
王银川, 李昭坤, 翟自峰等. 山西本溪组铝土矿成矿条件及成矿规律探讨[J]. 西北地质, 2011, 44(4): 82-88 doi: 10.3969/j.issn.1009-6248.2011.04.011
WANG Yinchuan, LI Zhaokun, ZHAI Zifeng, et al. Benxi Formation Bauxite Mineralization Condition and Rule in Shanxi Province[J]. Northwestern Geology, 2011, 44(4): 82-88. doi: 10.3969/j.issn.1009-6248.2011.04.011
|
|
徐友宁. 陕西某石煤矿集中开采区河流白色污染的形成机制与演化[R]. 全国土壤修复大会, 2021.
|
|
赵玲, 李官, 王荣锌. 金属矿山酸性废水治理技术现状与展望[J]. 中国资源综合利用, 2009, 27(10): 13-15 doi: 10.3969/j.issn.1008-9500.2009.10.008
ZHAO Ling, LI Guan, WANG Rongxin. Treatment Techniques and Developmental Trends of Metal Mines Acid Wastewater[J]. China Resources Comprehensive Utilization, 2009, 27(10): 13-15. doi: 10.3969/j.issn.1008-9500.2009.10.008
|
|
章丽萍. 浅谈铝污染与人体健康[J]. 大同医学专科学校学报, 2005(02): 27-28. doi: 10.1007/s11356-021-14700-0
Alasfar H Reema, Isaifan J Rima. Aluminum environmental pollution: the silent killer[J]. Environmental science and pollution research international, 2021, 28(33): 44587-44597. doi: 10.1007/s11356-021-14700-0
|
|
周闻达, 向武, 金丽, 等. 石煤矿山酸性废水自净化机理及防治对策[J]. 环境科学与技术, 2020, 43(08): 20-27 doi: 10.19672/j.cnki.1003-6504.2020.08.004
ZHOU Wenda, XIANG Wu, JIN Li, et al. The Self-purification Mechanism and Control Counter measures of Cadmium-rich Acid Mine Drainage of Stone Coal Mines[J]. Environmental Science & Technology, 2020, 43(08): 20-27. doi: 10.19672/j.cnki.1003-6504.2020.08.004
|
|
Alasfar H Reema, Isaifan J Rima. Aluminum environmental pollution: the silent killer[J]. Environmental science and pollution research international, 2021, 28(33): 44587-44597. doi: 10.1007/s11356-021-14700-0
|
|
Banfield J F, Eggleton R A. Analytical transmission electron microscope studies of plagioclase, muscovite, and K-feldspar weathering[J]. Clays and Clay Minerals, 1990, 38(1): 77-89. doi: 10.1346/CCMN.1990.0380111
|
|
Bao Y P, Guo C L, Lu G N, Yi X Y, Wang H, Dang Z. Role of microbial activity in Fe(III) hydroxysulfate mineral transformations in an acid mine drainage-impacted site from the Dabaoshan Mine[J]. Science of the Total Environment, 2018, 616-617: 647-657. doi: 10.1016/j.scitotenv.2017.10.273
|
|
Caraballo M A, Wanty R B, Verplanck P L, Navarro-Valdivia L, Ayora C, Hochella M F. Aluminum mobility in mildly acidic mine drainage: Interactions between hydrobasaluminite, silica and trace metals from the nano to the meso-scale[J]. Chemical Geology, 2019, 519: 1-10. doi: 10.1016/j.chemgeo.2019.04.013
|
|
Cong Lu, Bo Yang, Xing Cui, Sichang Wang, Chengtun Qu, Weiwei Zhang, Bo Zhou. Characteristics and Environmental Response of White Secondary Mineral Precipitate in the Acid Mine Drainage From Jinduicheng Mine, Shaanxi, China[J]. Bulletin of Environmental Contamination and Toxicology, 2021 107: 1012–1021. doi: 10.1007/s00128-021-03355-9
|
|
Furrer G, Phillips B L, Ulrich K-U, Pöthig R, Casey W. The origin of aluminum flocs in polluted streams[J]. Science, 2002, 297: 2245-2247. doi: 10.1126/science.1076505
|
|
Gilles G , Cecile G. Study of aluminium concentration and speciation of surface water in four catchments in the Limousin region (France)[J]. Journal of Inorganic Biochemistry 97 (2003) 16–25.
|
|
Igbokwe Onyebuchi Ikechukwu, Igwenagu Ephraim, Igbokwe Afifi Nanacha. Aluminium toxicosis: a review of toxic actions and effects[J]. Interdisciplinary toxicology, 2019, 12(2): 45-70. doi: 10.2478/intox-2019-0007
|
|
Kumar B, Singh U K. Source apportionment of heavy metals and their ecological risk in a tropical river basin system[J]. Environmental Science & Pollution Research, 2018, 25(25): 25443−25457.
|
|
Li M R, Li C C, Xing J T, Sun X T, Yuan G H, Cao Y C. An experimental study on dynamic coupling process of alkaline feldspar dissolution and secondary mineral precipitation[J]. Acta Geochimica, 2019, 38(6): 872-882. doi: 10.1007/s11631-019-00326-0
|
|
Liu Q Y, Chen B H, Haderlein S, Gopalakrishnan G, Zhou Y Z. Characteristics and environmental response of secondary minerals in AMD from Dabaoshan Mine, South China[J]. Ecotoxicology Environmental Safety, 2018, 155(1): 50-58. doi: 10.1126/science.232.4746.54
|
|
Manuel, M. A. , Grathwohl, P. , Johnson, K. W. , & Eberl, D. D. Natural and Anthropogenic Transport Mechanisms Drive the Formation and Fate of Aluminum Hydroxide Mineral Particles in Streams and Rivers[J]. Environmental Science & Technology, 2019, 53(2), 493–504.
|
|
Nordstrom D K, Ball J W. The geochemical behavior of aluminum in acidified surface waters[J]. Science, 1986, 232: 54-56. doi: 10.1126/science.232.4746.54
|
|
Sanchez España J. , Yusta I. , Burgos W. The geochemistry of dissolved aluminum at low pH: Hydrobasaluminite formation and interaction with silica, trace metals and microbial cells under anoxic conditions [J]. Chemical Geology, 2016, 192: 70-96.
|
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