Supervisor：China Geological Survey
Sponsored by：XI'an Center of China Geological Survey
Geological Society of China
| Citation: |
ZHAO Dacheng, WANG Meile, LI Zhangzhixian, et al. The Occurrence and Distribution of Cobalt and Nickel Key Metals in the Xiarihamu Magmatic Sulfide Deposit[J]. Northwestern Geology, 2023, 56(6): 17-40. DOI: 10.12401/j.nwg.2023121
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The industrial value of the Xiarihamu giant Ni–Co sulfide deposit in the East Kunlun orogenic belt, is not only depends on the content of Co and Ni elements in the minerals, but also on the occurrence state and spatial distribution pattern of Co and Ni elements. In this study, Borehole samples were analyzed by TESCAN Integrated Mineral Analyzer . It was determined that Co and Ni elements occur as isolated minerals and sulfur-arsenic mineral compositions. In-situ analysis of major and trace element analysis of the metal minerals in the Xiarihamu Ni–Co deposit have been carried out. The contents of Co in the minerals from high to low are as follows: cobaltine ＞ maucherite, bravoite, pentlandite ＞ niccolite, magnetite ＞ pyrrhotite, chalcopyrite; the contents of Ni in the minerals from high to low are as follows: maucherite, niccolite＞ bismuthite, bravoite, pentlandite ＞ cobaltine ＞ magnetite, pyrrhotite and chalcopyrite. Pyrrhotite, pentlandite and chalcopyrite were chosen for LA–ICP–MS trace elements and elements mapping analysis, the Co and Ni were uniform in pentlandite and chalcopyrite in the single particle mineral scales, and there are no obvious changes observed in Co/Ni ratios, these indicating that hydrothermal process did not affect the Co and Ni contents of pentlandites and chalcopyrites. However, Ni is heterogeneous in pyrrhotite, and the Co/Ni ratios varies from 0.01 to 0.63, indicating that the pyrrhotite is more sensitive to hydrothermal processes. In situ major and trace element analysis show that the contents of Co and Ni in pentlandite are close to that of isolated Co–Ni minerals, and far exceeds that of pyrrhotites and chalcopyrites. Therefore, the ore containing pentlandite has the most potential for Co and Ni resource exploretion.
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包亚文, 张铭杰, 闫继雄, 等. 夏日哈木镍钴硫化物矿床镍钴赋存状态及其地质意义[J]. 岩石学报, 2023, 39(04): 1061-1074 doi: 10.18654/1000-0569/2023.04.08
BAO Yawen, ZHANG Mingjie, YAN Jixiong, et al. The Ni-Co occurrence modes and geological significance of the Xiarihamu Ni-Co sulfide deposit, western China[J]. Acta Petrologica Sinica, 2023, 39(4): 1061-1074. doi: 10.18654/1000-0569/2023.04.08
|
|
杜玮. 东昆仑夏日哈木镍矿区镁铁-超镁铁质岩石研究[D]. 西安: 长安大学, 2015
DU Wei. Study on the mafic-ultramafic rocks of Xiarihamu Nickel Mining Area in East Kunlun[D]. Xi’an: Chang’an University, 2015.
|
|
杜玮. 东昆中岛弧带两类镁铁质—超镁铁质岩石与镍矿床研究[D]. 西安: 长安大学, 2018
DU Wei. Study on Two kinds of mafic ultramafic rocks and Nickel sulfide deposit in East Kunlun island arc zone[D]. Xi’an: Chang’an University, 2018.
|
|
段雪鹏, 孟繁聪, 范亚洲. 东昆仑夏日哈木镁铁-超镁铁岩中的钛闪石-韭闪石对成矿过程的约束[J]. 岩石学报, 2019, 35(06): 1819-1832 doi: 10.18654/1000-0569/2019.06.11
DUAN Xuepeng, MENG Fancong, FAN Yazhou. The constraints of kaersutite and pargasite on metallogeny in Xiarihamu mafic-ultramafic intrusion, East Kunlun[J]. Acta Petrologica Sinica, 2019, 35(6): 1819-1832. doi: 10.18654/1000-0569/2019.06.11
|
|
姜常义, 凌锦兰, 周伟, 等. 东昆仑夏日哈木镁铁质-超镁铁质岩体岩石成因与拉张型岛弧背景[J]. 岩石学报, 2015, 31(4): 1117–1136
JIANG Changyi, LING Jinglan, ZHOU Wei, et al. Petrogenesis of the Xiarihamu Ni-bearing layered mafic-ultramafic intrusion, East Kunlun: Implications for its extensional island arc environment[J]. Acta Petrologica Sinica, 2015, 31(4): 1117–1136.
|
|
李华, 蒋少涌, 李世金, 等. 东昆仑造山带岩浆型镍钴矿床地质特征、成因机制与找矿标志分析[J]. 岩石学报, 2023, 39(04): 1041-1060 doi: 10.18654/1000-0569/2023.04.07
LI Hua, JIANG Shaoyong, LI Shijin, et al. Geological characteristicsore genetic mechanism and exploration indicators of magmatic nicke-cobalt deposits in the East Kunlun Orogenic Belt[J]. Acta Petrologica Sinica, 2023, 39(04): 1041-1060. doi: 10.18654/1000-0569/2023.04.07
|
|
李艳广, 靳梦琪, 汪双双, 等. LA–ICP–MS U–Pb定年技术相关问题探讨[J]. 西北地质, 2023, 56(4): 274-282.
LI Yanguang, JIN Mengqi, WANG Shuangshuang, et al. Exploration of Issues Related to the LA–ICP–MS U–Pb Dating Technique[J]. Northwestern Geology, 2023, 56(4): 274−282.
|
|
刘超, 王亚磊, 张照伟, 等. 东昆仑夏日哈木矿床镍黄铁矿、磁黄铁矿成因认识及钴赋存特征[J]. 西北地质, 2020, 53(02): 183-199 doi: 10.19751/j.cnki.61-1149/p.2020.02.011
LIU Chao, WANG Yalei, ZHANG Zhaowei, et al. The Genetic Sianificance of Pentlandite and Pyrthotite and the Characteristics of Cobalt 0ccurence in Xiarihamu Cobalt-Nickel Deposit of Eastern Kunlun[J]. Northwest Geoscience, 2020, 53(02): 183-199. doi: 10.19751/j.cnki.61-1149/p.2020.02.011
|
|
潘彤, 陈克强, 李月隆. 青海省都兰县督冷沟铜-钴矿的发现过程与启示[J]. 矿产与地质, 2006, 20(04-05): 434-436 doi: 10.3969/j.issn.1001-5663.2006.04.021
PAN Tong, CHEN Keqiang, LI Yuelong. Discovery of Dulenggou copper and cobalt deposit in Dulan county, Qinghai province and its inspiration[J]. Mineral Resources and Geology, 2006, 20(4-5): 434-436. doi: 10.3969/j.issn.1001-5663.2006.04.021
|
|
潘彤, 马梅生, 康祥瑞. 东昆仑肯德可克及外围钴多金属矿找矿突破的启示[J]. 中国地质, 2001, 28(2): 17-20 doi: 10.3969/j.issn.1000-3657.2001.02.004
PAN Tong, MA Meisheng, KANG Xiangrui. Enlightenments of prospecting breakthrough in and around Kendekeke cobalt polymetallic deposit of east Kunlun region[J]. Chinese Geology, 2001, 28(2): 17-20. doi: 10.3969/j.issn.1000-3657.2001.02.004
|
|
苏本勋, 蒋少涌, 崔梦萌, 等. 钴镍成矿规律与勘查技术研究进展: 前言[J]. 岩石学报, 2023, 39(4): 963-967 doi: 10.18654/1000-0569/2023.04.01
SU Benxun, JIANG Shaoyong, CUI Mengmeng, et al. Progress in mineralization and prospecting technology of cobalt and nickel: Preface[J]. Acta Petrologica Sinica, 2023, 39(4): 963-967. doi: 10.18654/1000-0569/2023.04.01
|
|
汤庆艳, 李建平, 张铭杰, 等. 东昆仑夏日哈木镍铜硫化物矿床成矿岩浆条件: 流体挥发份化学组成与碳同位素组成制约[J]. 岩石学报, 2017, 33(01): 104-114
TANG Qinyan, LI Jianpin, ZHANG Mingjie, et al. The volatile conditions of ore-forming maama for the Xiarihamu Ni-Cu sulfide deposit in East Kunlun orogenic belt, western China: Constraints from chemical and carbon isotopic compositions of volatiles[J]. Acta Petrologica Sinica, 2017, 33(01): 104-114.
|
|
汪方跃, 葛粲, 宁思远, 等. 一个新的矿物面扫描分析方法开发和地质学应用[J]. 岩石学报, 2017, 33(11): 3422-3436
WANG Fangyue, GE Cui, NIN Siyuan, et al. A new approach to LA-ICP-MS mapping and application in geology[J]. Acta Petrologica Sinica, 2017, 33(11): 3422-3436.
|
|
王冠. 东昆仑造山带镍矿成矿作用研究[D]. 长春: 吉林大学, 2014
WANG Guan. Metallogenesis of Nickel deposits in Eastern Kunlun Orogenic Belt, Qinghai Province[D]. Jilin: Jilin University, 2014.
|
|
王冠, 孙丰月, 李碧乐, 等. 东昆仑夏日哈木铜镍矿镁铁质-超镁铁质岩体岩相学、锆石U-Pb年代学、地球化学及其构造意义[J]. 地学前缘, 2014, 21(06): 381-401
WANG Guan, SUN Fengyue, LI Bile, et al. Petrography, zircon U-Pb geochronology and geochemistry of the mafic-ultramafic intrusion in Xiarihamu Cu-Ni deposit from East Kunlun, with implications for geodynamic setting[J]. Earth Science Frontiers, 2014, 21(06): 381-401.
|
|
王小东, 张铭杰, 伏珏蓉, 等. 稀有气体同位素对岩浆侵入方向的制约: 以夏日哈木镍铜硫化物矿床为例[J]. 岩石学报, 2018, 234(11): 3433-3444
WANG Xiaodong, ZHANG Mingjie, FU Yurong, et al. The magmatic intrusive direction constrains from noble gas isotopic compositions: A case study of the Xiarihamu Ni-Cu sulfide deposit in East Kunlun orogenic belt, China[J]. Acta Petrologica Sinica, 2018, 234(11): 3433-3444.
|
|
王亚磊, 李文渊, 林艳海, 等. 金川超大型铜镍矿床钴的赋存状态与富集过程研究[J]. 西北地质, 2023, 56(2): 133−150.
WANG Yalei, LI Wenyuan, LIN Yanhai, et al. Study on the Occurrence State and Enrichment Process of Cobalt in Jinchuan Giant Magmatic Ni−Cu Sulfide Deposit[J]. Northwestern Geology, 2023, 56(2): 133−150.
|
|
王焰, 钟宏, 曹勇华, 等. 我国铂族元素、钴和铬主要矿床类型的分布特征及成矿机制[J]. 科学通报, 2020, 65: 3825-3838 doi: 10.1360/TB-2020-0202
WANG Yan, ZHONG Hong, CAO Yonghua, et al. Genetic classification, distribution and ore genesis of major PGE, Co and Cr deposits in China: A critical review[J]. Chinese Science Bulletin, 2020, 65: 3825-3838. doi: 10.1360/TB-2020-0202
|
|
王治安, 王彬, 杨启安, 等. 青海省第五地质矿产勘查院. 夏日哈木铜镍矿HS26号异常区11勘探线剖面图[R]. 西宁: 青海省第五地质矿产勘查院, 2014.
|
|
殷鸿福, 张克信. 东昆仑造山带的一些特点[J]. 地球科学, 1997, (04): 3-6 doi: 10.3321/j.issn:1000-2383.1997.04.001
YIN Hongfu, ZHANG Kexin. Characteristics of the Eastern Kunlun Orogenic Belt[J]. Earth Science, 1997, (04): 3-6. doi: 10.3321/j.issn:1000-2383.1997.04.001
|
|
张洪瑞, 侯增谦, 杨志明, 等. 钴矿床类型划分初探及其对特提斯钴矿带的指示意义[J]. 矿床地质, 2020, 39(3): 501-510 doi: 10.16111/j.0258-7106.2020.03.007
ZHANG Hongrui, HOU Zengqian, YANG Zhiming, et al. A new division of genetic types of cobalt deposits: Implications for Tethyan cobalt-rich belt[J]. Mineral Deposits, 2020, 39(3): 501-510. doi: 10.16111/j.0258-7106.2020.03.007
|
|
张连昌, 张爱奎, 刘永乐, 等. 沉积岩-变沉积岩型钴矿研究进展与问题[J]. 岩石学报, 2023, 39(04): 0981-0997.
ZHANG Lianchang, ZHANG Aikui, LIU Yongle, et al. Research progresses and problems of sedimentary-metasedimentary rock-hosted cobalt deposits[J]. Acta Petrologica Sinica, 2023, 39(4): 981-997.
|
|
张照伟, 李文渊, 钱兵, 等. 东昆仑夏日哈木岩浆铜镍硫化物矿床成矿时代的厘定及其找矿意义[J]. 中国地质, 2015, 42(03): 438-451 doi: 10.3969/j.issn.1000-3657.2015.03.004
ZHANG Zhaowei, LI Wenyuan, QIAN Bin, et al. Metallogenic epoch of the Xiarihamu maqmatic Ni-Cu sulfide deposit in eastern Kunlun orogenic belt and its prospecting sianificance[J]. Geology in China, 2015, 42(03): 438-451. doi: 10.3969/j.issn.1000-3657.2015.03.004
|
|
张照伟, 王亚磊, 钱兵, 等. 东昆仑石头坑德镁铁-超镁铁质岩体矿物学特征及成矿指示[J]. 地质与勘探, 2017, 53(05): 825-837 doi: 10.13712/j.cnki.dzykt.2017.05.001
ZHANG Zhaowei, WANG Yalei, QIAN Bin, et al. Mineralogical Characteristics of the Shitoukengde Mafic-Ultramafic Intrusions in East Kunlun Orogenic Belt and the Ore-Forming Indication[J]. Geology and Exploration, 2017, 53(05): 825-837. doi: 10.13712/j.cnki.dzykt.2017.05.001
|
|
张照伟, 王驰源, 刘超, 等. 东昆仑夏日哈木矿区岩体含矿性特点与形成机理探讨[J]. 西北地质, 2019, 52(03): 35-45 doi: 10.19751/j.cnki.61-1149/p.2019.03.004
ZHANG Zhaowei, WAGN Chiyuan, LIU Chao, et al. Mineralization Characteristics and Formation Mechanism of the Intrusions in Xiarihamu Magmatic Ni-Cu Sulfide Deposit East Kunlun Orogenic Belt, Northwest China[J]. Northwest Geoscience, 2019, 52(03): 35-45. doi: 10.19751/j.cnki.61-1149/p.2019.03.004
|
|
张照伟, 李文渊, 丰成友, 等. 中国钴-镍成矿规律与高效勘查技术[J]. 西北地质, 2022, 55(2): 14-34
ZHANG Zhaowei, LI Wenyuan, FENG Chengyou, et al. Study on Metallogenic Regularity of Co-Ni Deposits in China and Its Efficient Exploration Techniques[J]. Northwest Geoscience, 2022, 55(2): 14-34.
|
|
张志炳, 李文渊, 张照伟, 等. 东昆仑夏日哈木岩浆铜镍硫化物矿床铬尖晶石特征及其指示意义[J]. 矿物岩石地球化学通报, 2016, 35(05): 966-975 doi: 10.3969/j.issn.1007-2802.2016.05.017
ZHANG Zhibin, LI Wenyuan, ZHANG Zhaowei, et al. Characteristics of Chromian Spinels from the Xiarihamu Magmatic Ni-Cu Sulfide Ore Deposit in the Eastern Kunlun Orogenic Belt, Northwest China and Their Implication[J]. Bulletin of Mineralogy, Petrology and Geochemistry, 2016, 35(05): 966-975. doi: 10.3969/j.issn.1007-2802.2016.05.017
|
|
Chen L M, Song X Y, Hu R Z, et al. Mg-Sr-Nd Isotopic Insights into Petrogenesis of the Xiarihamu Mafic-Ultramafic Intrusion, Northern Tibetan Plateau, China[J]. Journal of Petrology, 2021, 62(2): 1-25.
|
|
Han Y X, Liu Y H, Li W Y. Mineralogy of Nickel and Cobalt Minerals in Xiarihamu Nickel–Cobalt Deposit, East Kunlun Orogen, China[J]. Frontiers in Earth Science, 2020, 8: 597-469.
|
|
Li H R, Qian Y, Sun F Y, et al. Zircon U-Pb dating and sulfide Re-Os isotopes of the Xiarihamu Cu-Ni sulfide deposit in Qinghai Province, NW China[J]. Canadian Journal of Earth Sciences, 2020, 57(8): 885-902. doi: 10.1139/cjes-2019-0107
|
|
Li C S, Zhang Z W, Li W Y, et al. Geochronology, petrology and Hf-S isotope geochemistry of the newly-discovered Xiarihamu magmatic Ni-Cu sulfide deposit in the Qinhai-Tibet plateau, western China[J]. Lithos, 2015, 216-217: 224-240. doi: 10.1016/j.lithos.2015.01.003
|
|
Liu Y G, Li W Y, Jia Q Z, et al. The Dynamic Sulfide Saturation Process and a Possible Slab Break-off Model for the Giant Xiarihamu Magmatic Nickel Ore Deposit in the East Kunlun Orogenic Belt, Northern Qinghai-Tibet Plateau, China[J]. Economic Geology, 2018, 113(6): 1383-1417. doi: 10.5382/econgeo.2018.4596
|
|
Peng B, Sun F Y, Li B L, et al. The geochemistry and geochronology of the Xiarihamu II mafic-ultramafic complex, Eastern Kunlun, Qinghai Province, China: Implications for the genesis of magmatic Ni-Cu sulfide deposits[J]. Ore Geology Reviews, 2016, 73: 13-28. doi: 10.1016/j.oregeorev.2015.10.014
|
|
Song G Y, Gong Q S, Pang H. High-precision sequence stratigraphy and sand‐body architecture of the Lower Xiaganchaigou Formation in theslope area of western Qaidam Basin[J]. Geology in China, 2020, 47(1): 188-200.
|
|
Song X Y, Yi J N, Chen L M, et al. The Giant Xiarihamu Ni-Co Sulfide Deposit in the East Kunlun Orogenic Belt, Northern Tibet Plateau, China[J]. Economic Geology, 2016, 111: 29-55. doi: 10.2113/econgeo.111.1.29
|
|
USGS, Mineral commodity summaries[R]. U. S. Geological Survey, 2019.
|
|
Xiao X, Zhou T F, White N C. The formation and trace elements of garnet in the skarn zone from the Xinqiao Cu-S-Fe-Au deposit, Tongling ore district, Anhui Province, eastern China[J]. Lithos, 2018, 302: 467-479.
|
|
Zhang Z W, Tang Q Y, Li C S, et al. Sr-Nd-Os-S isotope and PGE geochemistry of the Xiarihamu magmatic sulfide deposit in the Qinghai-Tibet plateau, China[J]. Mineralium Deposita, 2016, 52(1): 51-68.
|
|
Zhang M J, Liu Y G, Chen A P, et al. The tectonic links between Palaeozoic eclogites and mafic magmatic Cu-Ni-Co mineralization in East Kunlun orogenic belt, western China[J]. International Geology Review, 2023, 65: 1158-1178. doi: 10.1080/00206814.2021.1885504
|
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