ISSN 1009-6248CN 61-1149/P 双月刊

主管单位:中国地质调查局

主办单位:中国地质调查局西安地质调查中心
中国地质学会

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    内蒙古中东部玛尼吐组火山岩形成时代及其大地构造环境

    柳永正, 张海平, 张永清, 贺宏云, 徐铭池, 焦建刚

    柳永正, 张海平, 张永清, 等. 内蒙古中东部玛尼吐组火山岩形成时代及其大地构造环境[J]. 西北地质, 2023, 56(2): 46-60. DOI: 10.12401/j.nwg.2023001
    引用本文: 柳永正, 张海平, 张永清, 等. 内蒙古中东部玛尼吐组火山岩形成时代及其大地构造环境[J]. 西北地质, 2023, 56(2): 46-60. DOI: 10.12401/j.nwg.2023001
    LIU Yongzheng, ZHANG Haiping, ZHANG Yongqing, et al. Zircon U–Pb Age and Tectonic Setting of the Manitu Formation in the Middle–East Inner Mongolia, China[J]. Northwestern Geology, 2023, 56(2): 46-60. DOI: 10.12401/j.nwg.2023001
    Citation: LIU Yongzheng, ZHANG Haiping, ZHANG Yongqing, et al. Zircon U–Pb Age and Tectonic Setting of the Manitu Formation in the Middle–East Inner Mongolia, China[J]. Northwestern Geology, 2023, 56(2): 46-60. DOI: 10.12401/j.nwg.2023001

    内蒙古中东部玛尼吐组火山岩形成时代及其大地构造环境

    基金项目: 中国地质调查局项目“中国区域地质志·内蒙古志”(121201130132001),内蒙古自然科学基金项目“内蒙古自治区地质勘查基金项目”(2020-KY05)联合资助。
    详细信息
      作者简介:

      柳永正(1969−),男,高级工程师,从事野外区域地质调查工作。E–mail:nmgliuyongzheng@qq.com

      通讯作者:

      焦建刚(1976−),男,博士,教授,主要从事矿床学研究与教学。E–mail:jiangang@chd.edu.cn

    • 中图分类号: P581;P597.3

    Zircon U–Pb Age and Tectonic Setting of the Manitu Formation in the Middle–East Inner Mongolia, China

    • 摘要:

      玛尼吐组广泛分布在内蒙古中东部地区,长期以来与满克头鄂博组和白音高老组的地质时代被定为晚侏罗世,然而前人在玛尼吐组中发现Nestoriapissovi化石,并认为是早白垩世冀北阶的带化石,同位素年代学结果差异也较大,而且形成的大地构造环境仍然存在争论。因此,笔者对玛尼吐组火山岩进行了同位素年代学分析,并利用全岩成分探讨其形成的大地构造环境。玛尼吐组采集的3个安山岩和粗安岩的锆石U–Pb (LA–ICP–MS)测年结果分别为(142.4±1.4)Ma、(130.0±1.4)Ma和(145.0±1.5)Ma,显示该地区玛尼吐组形成于早白垩世。样品SiO2含量为59.43%~64.73%,Al2O3含量为15.66%~17.19%,K2O含量为2.56%~5.03%,Na2O含量为3.59%~4.53%,全碱含量为6.36%~9.56%;微量元素以富集大离子亲石元素和LREE,亏损Nb、Sr、P和Ti为特征;稀土元素ΣREE=118.71×106~189.99×106,轻重稀土分馏系数 (La/Yb)N为8.88~9.58,δEu值为0.66~0.95,Eu负异常,与岛弧火山岩地球化学特征相似。对比大兴安岭西部玛尼吐组西部、中部(~140 Ma)和东部火山岩年龄,笔者认为其玛尼图组火山岩类最老形成于晚侏罗世(~158 Ma),向东逐渐变新为早白垩世(140~130 Ma),这一变化与蒙古–鄂霍次克洋自西向东的闭合及陆块的后碰撞伸展有关。

      Abstract:

      The Manitu Formation widely occurs in the middle–east Inner Mongolia Autonomous region, and was thought to be formed in the late Jurassic together with the regional Manketouebo Formation and the Baiyingaolao Formation. However, the Nestoriapissovi fossils in the andesite interlayer of the Manitu Formation indicate this formation was formed during the Jibei Stage of the early cretaceous by previous studies. In addition, the zircon U–Pb ages for the volcanic rocks in the Manitu Formation have a wide range, and the tectonic setting is still under debate. Therefore, this study carried out the analyses of zircon U–Pb dating and whole–rock compositions to examine the age and tectonic setting of the Manitu Formation. The zircon U–Pb ages for three samples collected from Zarutqi–Bahrainyouqi are 142.4±1.4Ma, 130.0±1.4Ma and 145.0±1.5Ma, respectively, suggesting the Manitu Formation in the Zarutqi–Bahrainyouqi area were formed in the early Cretaceous. Rocks from the Manitu Formation have SiO2, Al2O3, K2O and Na2O of 59.43%~64.73%, 15.66%~17.19%, 2.56%~5.03%, 3.59%~4.53%, respectively, with ALK of 6.36%~9.56%. They have high concentration of LILE and LREE, and depletion of Nb, Sr, P and Ti. Total rare earth element (ΣREE) concentration ranges from 118.71×10–6 to 189.99×10–6, and LREE and HREE are highly fractionated with (La/Yb)N of 8.88~9.58, with negative Eu anomalies (δEu=0.66~0.95), showing an island arc–like geochemistry. We propose that the formation age becomes younger from the west to east of the Great Xing’an Mountain based on the comparison of ages of rocks from the west, middle and east segment, and this may ascribed to the closure of the Mongol–Okhotsk ocean and the subsequent post–collision extension.

    • 图  1   大兴安岭中南段区域地质略图及采样位置

      1.盖层;2.前中生代基底;3.白音高老组;4.玛尼吐组;5.满克头鄂博组;6.早白垩世花岗岩;7.晚侏罗世花岗岩;8.地质界线;9.同位素采样位置及编号

      Figure  1.   Regional geological sketch map and sampling positions in the middle–south part of the Daxinganling region

      图  2   大兴安岭中南段玛尼吐组样品显微照片

      a、b.样品TW2326;c、d.样品TW2327;e、f.样品TW2331;a、c、e .单偏光; b、d、f .正交偏光;Cc.方解石 (Calcite);Chl.绿泥石;Hb.普通角闪石;Mt.磁铁矿;Pl.斜长石

      Figure  2.   Photomircrography of the volcanic rocks of the Manitu Formation in the middle–south part of the Daxinganling region

      图  3   玛尼吐组锆石CL图像和LA–ICP–MS分析点

      Figure  3.   Zircon CL images and analyzed points for the LA–ICP–MS measurements from the samples of the Manitu Formation

      图  4   大兴安岭中南部玛尼吐组LA–ICP–MS 锆石U–Pb年龄谐和图和加权平均年龄图

      a、b.样品TW2326;c、d.样品TW2327;e、f.样品TW2331

      Figure  4.   LA–ICP–MS U–Pb concordia diagram and weighted average age of zircon grains from Manitu Formation

      图  5   玛尼吐组样品全岩(K2O+Na2O)–SiO2图解(a)和K2O–SiO2图解 (b)(据Maitre et al.,2002

      Figure  5.   (a) (K2O+Na2O) versus SiO2 diagram and (b) K2O versus SiO2 diagram for samples from the Manitu Formation

      图  6   玛尼吐组流纹岩原始地幔标准化微量元素蛛网图 (a) 和球粒陨石标准化稀土元素配分模式图 (b) (据Sun et al.,1989

      Figure  6.   (a) Primitive mantle normalized trace element spider diagrams and (b) chondrite–normalized rare–earth element patterns for rhyolite from the Manitu Formation

      图  7   玛尼吐组大地构造环境判别图解

      a.底图据 (Pearce等(1984));b.底图据 (Wood(1980)

      Figure  7.   Tectonic discrimination diagrams of the samples from the Manitu Formation

      表  1   大兴安岭中南部玛尼吐组锆石U–Pb年龄

      Table  1   U–Pb ages of zircons from samples of the Manitu Formation in the middle–south Daxinganling region

      点号元素含量(10−6Th/U同位素比值年龄 (Ma)
      PbUTh206Pb/238Pb207Pb/235Pb207Pb/206Pb206Pb/238U207Pb/235Pb
      TW2326.183161040.330.023490.000640.167690.019900.051280.00587149.692.87157.4111.93
      TW2326.283631110.310.023260.000440.163730.016550.050890.00487148.252.12153.9610.18
      TW2326.33515284010.260.023200.000340.168170.004710.052570.00117147.831.74157.833.06
      TW2326.4104831400.290.021440.000340.153520.013260.051880.00434136.731.86145.028.72
      TW2326.5289656860.710.023890.000300.315060.014320.095530.00385152.211.57278.094.71
      TW2326.62810603940.370.023980.000440.292150.024230.086340.00576152.752.06260.258.39
      TW2326.7125601950.350.019570.000360.273140.019190.100640.00583124.922.09245.207.14
      TW2326.82610975060.460.023080.000330.147910.005680.046500.00163147.111.72140.064.03
      TW2326.994091060.260.022470.000310.154330.015220.049590.00473143.271.66145.739.94
      TW2326.102912725000.390.022550.000370.166310.005970.053360.00146143.771.89156.213.80
      TW2326.114415493960.260.025700.000210.339950.009210.095970.00238163.581.24297.132.98
      TW2326.12685782030.350.054870.002383.877650.248110.501580.01341344.354.441609.046.52
      TW2326.13198542410.280.022440.000280.159450.007150.051560.00220143.081.56150.224.65
      下载: 导出CSV
      续表1
      点号元素含量(10−6Th/U同位素比值年龄 (Ma)
      PbUTh206Pb/238Pb207Pb/235Pb207Pb/206Pb206Pb/238U207Pb/235Pb
      TW2326.14167341530.210.022240.000300.149770.007230.048870.00227141.791.63141.714.98
      TW2326.153414494980.340.023150.000470.164440.005720.051470.00131147.562.23154.583.69
      TW2326.169382950.250.022510.000390.169420.014980.054280.00454143.521.98158.918.93
      TW2326.175219770.350.023200.000340.168280.025440.052760.00814147.821.76157.9315.17
      TW2326.189388880.230.022780.000380.158950.015210.050450.00461145.231.91149.789.65
      TW2326.192410522940.280.022360.000350.213810.009270.068990.00231142.531.81196.754.51
      TW2326.203716523710.220.023190.000410.154790.004210.048470.00103147.761.99146.142.99
      TW2326.216280670.240.022430.000340.138190.017370.044410.00542143.011.77131.4312.63
      TW2326.227324720.220.022980.000430.158590.017740.049790.00541146.442.10149.4711.25
      TW2326.2310311880.280.025510.000340.584790.021730.166460.00575162.391.65467.543.92
      TW2326.248335980.290.022390.000320.162040.017530.052440.00555142.721.71152.4910.89
      TW2326.25188023720.460.022080.000290.155260.007450.051040.00234140.781.60146.544.96
      TW2326.265315595170.330.025510.000540.602670.030350.169540.00563162.382.30478.935.19
      TW2326.278271860.320.024610.000390.431850.021080.127090.00571156.751.86364.495.04
      TW2326.283114014790.340.021690.000290.160720.005950.053670.00164138.311.65151.343.90
      TW2326.29198043310.410.022870.000470.153020.007860.048610.00220145.792.27144.575.28
      TW2326.307292900.310.022170.000240.167460.020990.054780.00685141.361.42157.2112.60
      TW2326.3193991310.330.021840.000260.153260.012820.050850.00416139.301.51144.798.46
      TW2326.322711386070.530.021580.000360.179520.006790.060120.00170137.611.92167.653.98
      TW2326.333715846100.380.022690.000360.162300.005220.051780.00126144.651.83152.713.45
      TW2326.34104601870.410.021750.000260.168110.011660.056030.00375138.721.51157.787.05
      TW2326.35125223960.760.021460.000320.150500.010780.050780.00344136.891.76142.357.27
      TW2326.3610017088470.500.031570.001051.341530.125760.293840.01826200.393.44863.899.46
      TW2326.37156622940.440.021790.000310.150820.007830.050190.00247138.931.70142.635.34
      TW2326.3883631420.390.021710.000330.147200.014460.049180.00474138.441.78139.449.90
      TW2326.393113444820.360.022300.000450.183010.007830.059160.00169142.152.22170.654.45
      TW2326.4072951320.450.022410.000850.296290.087780.080970.01664142.853.90263.5029.65
      TW2326.413816885490.330.022510.000390.154310.004390.049730.00106143.521.97145.713.10
      TW2326.424194650.330.021760.000380.159560.027590.053170.00903138.762.00150.3217.34
      TW2327.1173425111.500.024780.000180.661690.018200.191290.00451157.771.18515.653.02
      TW2327.22610349310.900.020270.000170.291310.004240.104320.00106129.381.25259.591.91
      TW2327.351152702.340.024820.000220.138330.014270.040620.00410158.051.28131.5610.39
      TW2327.41333910523.100.021420.000170.163900.004680.055530.00148136.611.22154.113.11
      TW2327.591434293.010.026400.000210.265080.010920.073320.00291167.991.24238.754.30
      TW2327.6102457743.160.023710.000190.151350.006130.046470.00181151.071.22143.104.24
      TW2327.72471513141.840.021440.000180.209000.003620.071510.00119136.731.25192.722.13
      TW2327.836126021331.690.020500.000150.142880.001960.050530.00047130.821.21135.611.85
      TW2327.943105624142.290.018630.000200.279460.004050.110910.00160 119.001.44250.231.91
      TW2327.10144718891.890.020560.000160.143070.003510.050530.00113131.221.21135.772.75
      TW2327.112788716281.840.020560.000170.155230.002510.054820.00070131.201.24146.522.04
      TW2327.1238147020631.400.019830.000150.133480.001730.048890.00044126.561.19127.221.80
      TW2327.1372064172.030.020600.000160.179780.007310.063060.00248131.481.22167.874.25
      TW2327.1482405832.420.020480.000160.126360.006610.044740.00223130.711.22120.825.38
      下载: 导出CSV
      续表1
      点号元素含量(10−6Th/U同位素比值 年龄 (Ma)
      PbUTh206Pb/238Pb207Pb/235Pb207Pb/206Pb206Pb/238U207Pb/235Pb
      TW2327.1537133421371.600.019940.000140.160860.002020.058540.00050127.281.16151.461.76
      TW2327.16102937462.540.020330.000160.158330.005420.056370.00180129.731.23149.243.64
      TW2327.17112849123.210.020170.000140.147900.005370.053210.00187128.701.18140.053.83
      TW2327.18176828211.200.020050.000140.152240.003410.055020.00111127.941.16143.892.56
      TW2327.1938144619591.360.020500.000160.140320.001860.049650.00043130.811.21133.331.82
      TW2327.202581292.250.020380.000260.205320.026760.070190.00939130.041.60189.6213.09
      TW2327.2149183924141.310.020860.000170.142430.001960.049410.00038133.101.25135.211.85
      TW2327.22182155172.400.047580.000380.406770.011000.061750.00147299.641.23346.552.98
      TW2331.1197613420.450.023470.000190.196090.003860.060260.00095149.581.23181.822.33
      TW2331.2198093050.380.022900.000180.188810.003710.059360.00088145.931.23175.612.32
      TW2331.38337970.290.022970.000190.205690.008650.063500.00234146.401.26189.934.38
      TW2331.4114691200.260.022920.000180.158070.003900.050130.00113146.061.24149.012.76
      TW2331.5248082870.350.026570.000260.332950.007890.088650.00152169.041.35291.822.67
      TW2331.6218714560.520.023430.000200.155820.002850.047980.00066149.301.26147.042.21
      TW2331.7114651400.300.024580.000200.171160.004250.050540.00115156.511.25160.422.78
      TW2331.8156382000.310.023830.000210.185550.004040.055970.00095151.801.28172.822.50
      TW2331.94621076290.300.021290.000170.168660.002590.057240.00053135.811.24158.261.97
      TW2331.10177252820.390.022730.000190.153840.002880.049050.00075144.901.25145.302.25
      TW2331.113614915290.350.021960.000160.251960.005170.082480.00136140.041.19228.172.40
      TW2331.129305830.270.025050.000200.367000.006850.106630.00175159.491.23317.432.24
      TW2331.13166591850.280.024940.000230.189640.004070.054880.00094158.781.31176.322.48
      TW2331.14136101350.220.021890.000160.152360.003280.050480.00098139.601.19144.002.48
      TW2331.153214305130.360.022060.000180.186440.002230.061660.00056140.641.24173.581.72
      TW2331.16175111410.280.034390.000240.242250.004490.051130.00083217.951.16220.262.23
      TW2331.174017744750.270.022740.000180.170570.002660.054160.00054144.981.24159.911.99
      TW2331.183514127430.530.022240.000170.215830.002780.070370.00056141.781.20198.431.79
      TW2331.1994031000.250.021990.000170.146910.004320.048450.00133140.231.22139.183.19
      TW2331.20104941080.220.020890.000170.161560.005110.055830.00163133.281.26152.063.39
      TW2331.215716217380.450.025960.000210.657290.007930.184300.00151165.241.25512.961.73
      TW2331.22219573070.320.022420.000180.153130.002370.049540.00059142.921.22144.681.98
      TW2331.237811974240.350.036920.000641.943080.082520.340790.01091233.741.961096.064.42
      TW2331.24243741540.410.037140.000331.667870.026620.327990.00454235.051.29996.382.02
      TW2331.257291880.300.023340.000210.122890.005640.038380.00168148.731.29117.694.75
      TW2331.26187913070.390.022570.000180.152030.002830.048920.00077143.891.22143.702.24
      TW2331.277259690.270.023930.000260.377600.016180.107880.00386152.421.45325.274.46
      TW2331.28228993030.340.023840.000210.187370.003710.056440.00079151.861.28174.382.34
      TW2331.298369920.250.022590.000190.181770.005120.058170.00148143.991.26169.583.08
      TW2331.30239843320.340.022690.000200.152380.002430.048730.00057144.661.29144.012.02
      TW2331.31155342470.460.026580.000260.191740.004030.052150.00090169.091.36178.112.44
      TW2331.32166942560.370.022810.000190.163390.003230.051860.00083145.371.27153.672.33
      TW2331.336283720.250.022670.000180.183980.007130.058620.00215144.541.24171.484.07
      TW2331.34197551710.230.024750.000220.251840.005020.074550.00142157.591.30228.072.35
      TW2331.353314684320.290.022320.000170.187730.002350.061050.00049142.271.20174.691.76
      下载: 导出CSV
      续表1
      点号元素含量(10−6Th/U同位素比值 年龄 (Ma)
      PbUTh206Pb/238Pb207Pb/235Pb207Pb/206Pb206Pb/238U207Pb/235Pb
      TW2331.36268102160.270.026710.000230.490230.010100.132060.00218169.921.27405.072.40
      TW2331.372510792310.210.023620.000200.164490.002390.050660.00056150.511.25154.631.91
      TW2331.382611273120.280.023410.000180.163700.002270.050710.00048149.191.22153.941.86
      TW2331.39218862040.230.024090.000210.167960.002660.050990.00071153.441.29157.642.01
      TW2331.402910292820.270.024340.000230.369830.009760.107910.00211155.031.32319.532.91
       注:测试单位为内蒙古自治区岩浆活动成矿与找矿重点实验室。
      下载: 导出CSV

      表  2   玛尼吐组火山岩全岩主量 (%) 和微量元素(10−6) 组成及相关地球化学参数

      Table  2   Major (%) and trace element (10−6) contents and related parameters of the Manitu Formation

      样号SiO2Al2O3Fe2O3FeOCaOMgOK2ONa2OTiO2P2O5MnO灼失总量ALKA/NKA/CNK
      TW232659.4315.674.761.304.562.342.563.800.890.220.0734.1599.7536.361.7370.905
      TW232758.9417.195.350.791.391.135.034.530.810.400.0934.1799.8239.561.3331.114
      TW233164.7315.663.462.072.180.774.233.590.720.190.111.9699.677.821.4941.084
      样号QAnAbOrAPCDiHyIlMtApDISIσAR
      TW232615.2219.0133.7115.8631.1937.3902.577.241.774.090.5364.7916.082.301.92
      TW23279.614.4940.1731.1566.269.552.8504.41.614.750.9780.936.85.352.90
      TW233122.189.831.1125.648.118.411.7103.581.44.170.4578.895.482.752.35
      样号CrNiCoRbCsSrBaVScNbTaZrHfGaUTh
      TW232616235.417.261.34.2254559812612.44.960.382225.7020.61.827.10
      TW23272.452.958.011253.7338983665.010.67.950.482275.4420.61.645.59
      TW23317.532.457.511547.8930181552.28.2914.41.432637.0524.06.4218.6
      样号LaCePrNdSmEuGdTbDyHoErTmYbLuYΣREE
      TW232634.767.68.5831.26.040.244.980.764.210.781.920.261.640.2420.7118.71
      TW232722.446.86.3123.55.011.284.180.663.720.721.860.181.810.2820.3132.23
      TW233127.652.66.8324.94.881.444.200.643.690.732.000.312.080.3320.1189.99
      样号LREEHREELREE/HREELaN/YbNδEuδCe
      TW2326105.3033.717.858.880.830.95
      TW2327118.2534.088.469.520.950.91
      TW2331169.9449.458.489.580.660.95
       注:测试单位为河北省区域地质矿产调查研究所实验室。
      下载: 导出CSV

      表  3   玛尼吐组同位素年龄按阶统计表

      Table  3   Compilation of the formation ages of the Manitu Formation

      晚侏罗世 早白垩世
      卡洛维阶牛津阶基默里奇阶提塘阶贝里阿斯阶凡兰吟阶欧特里沃阶巴列姆阶阿普特阶
      冀北阶热河阶
      (166.1±1.2)~
      (163.5±1)Ma
      (163.5±1.0)~
      (157.3±1)Ma
      (157.3±1.0)~
      (152.1±0.9)Ma
      (152.1±0.9)~
      (145±0.8)Ma
      (145.0±0.8)~
      139.8 Ma
      139.8~
      132.9 Ma
      132.9~
      129.4 Ma
      129.4~
      125.0 Ma
      125.0~
      113.0 Ma
      孙德有等,2011杜岳丹,2017崔玉斌等,2021邵济安等,1999林强等,1988付俊彧等,2018崔玉斌等,2021张慧婷等,2019邵积东等,2011
      下载: 导出CSV
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