ISSN 1009-6248CN 61-1149/P 双月刊

主管单位:中国地质调查局

主办单位:中国地质调查局西安地质调查中心
中国地质学会

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    某化工厂土壤与地下水Cr6+污染分布及健康风险

    Distribution and Health Risk Assessment of Cr6+ in Soil and Groundwater of a Chemical Plant

    • 摘要: 为掌握某化工厂Cr6+污染状况及风险水平,在研究区布设土壤与地下水采样点各19个,测定Cr6+含量,分析污染特征与成因,并开展健康风险评估。结果表明:表层土壤(0~0.5 m)Cr6+超标率为42.11%,其浓度随深度增加总体上降低,但在地下水位附近(15~20 m)回升,主要因长期淋溶作用使污染物向下迁移至含水层位富集。浅层地下水Cr6+超标率为73.68%,深层地下水超标率为37.50%。整体而言该区土壤和地下水Cr6+污染形势不容乐观,应开展水土协同治理。空间上表层土壤Cr6+分布受人类活动影响,与投产期厂内功能区的划分相关性较低。地下水Cr6+受水动力场影响,表现为西北高东南低,污染羽中心向下游方向迁移。土壤致癌风险均值为1.85×10−6,介于10−6~10−4,风险中等,应引起必要重视。非致癌风险低于1,无慢性毒害影响。经口摄入土壤为主要暴露途径。地下水致癌风险高达10−2数量级,远超过10−4,风险不可接受。非致癌风险均值51.62,远大于1,极可能引发慢性毒害效应。另外需进一步考虑Cr6+通过牛羊肉食物链进入人体的危害。

       

      Abstract: In order to clarify the Cr6+ pollution status and risk level of a chemical plant, 19 soil and groundwater sampling points were laid in the study area, and the content of Cr6+ was measured, to analyze the pollution characteristics and causes, and to carry out health risk assessment. The results showed that the excess rate of Cr6+ in topsoil (0~0.5 m) was 42.11%. In general, the Cr6+ concentration in soil decreased with the increase of depth, but it rose up near the groundwater level (15~20 m), which was mainly due to the long-term leaching effect that the pollutants migrated down to the aquifer and enriched. The excess rate of Cr6+ in shallow and deep groundwater was 73.68% and 37.50%, respectively. Overall, the Cr6+ pollution is not optimistic, and comprehensive water-soil treatment should be carried out. At the spatial scale the distribution of Cr6+ in topsoil was affected by human activities, and had a low correlation with the division of functional zones. And under the influence of hydrodynamic field, Cr6+ in groundwater is higher in the northwest than the southeast, and the center of the pollution plume has migrated downstream. In addition, the mean value of soil carcinogenic risk is 1.85×10−6, which is between 10−6 and 10−4, and the risk is moderate, which should be paid more attention to. Soil non-carcinogenic risk is less than 1 and doesn’t produce chronic toxic effects. Oral ingestion of soil was the main exposure route. The carcinogenic risk of groundwater is up to the order of 10−2, much more than 10−4, which is unacceptable. The average non-carcinogenic risk is 51.62, much higher than 1, which may cause chronic toxic effects. In addition, the health hazards caused by Cr6+ entering the human body through the beef and mutton food chain should be further studied.

       

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