ISSN 1009-6248CN 61-1149/P 双月刊

主管单位:中国地质调查局

主办单位:中国地质调查局西安地质调查中心
中国地质学会

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    肥城市地下水中重(类)金属的来源解析及健康风险评价

    Source Analysis and Health Risk Assessment of Heavy Metals (Metalloids) in Groundwater of Feicheng City, China

    • 摘要: 为查明泰安市肥城市地下水环境风险状况,本研究通过网格法系统采集了地下水样品77件,分析了Fe、Mn、Cu、Zn、Cd、Hg、As、Pb、Ni、Co、Sr、Cr(VI)等12项重(类)金属指标及pH值。结果表明,As和Cr(VI)指标均未检出,其余指标有不同程度的检出。研究区地下水中检出的10种重金属浓度平均值大小顺序为:Fe>Mn>Zn>Ni>Cu>Pb>Sr>Co>Cd>Hg。其中,ρ(Fe)和ρ(Mn)的浓度最高,为138~2187 μg/L和0.45~136 μg/L,平均值分别为857 μg/L和13.9 μg/L。单因子评价和综合指数评价表明,影响研究区地下水水质的主要污染因子是Fe、Pb、Zn和Mn。研究区94.8%的地下水样品中Fe浓度超出《地下水质量标准》(GB/T 14848—2017)中Ⅲ类限值;Fe、Mn、Co、Ni的来源为地质成因,Pb、Cd为交通和工业成因,Cu、Zn为农业成因。地下水健康风险较低,通过饮水途径引起的非致癌风险是本区域地下水健康暴露的主要途径和风险。Fe是非致癌健康风险的主要因素,健康风险值高低顺序为Fe>Pb>Mn>Co>Cu>Zn>Ni>Hg。

       

      Abstract: To assess the risk of groundwater environment in Feicheng of Tai’an City, 77 samples were collected to analyze 12 heavy metals (metalloids) and pH in the groundwater according to the griding sampling method. The results showed that As and Cr(VI) were not detected, while the other 10 heavy metals were detected with different detection frequencies. The order of average concentrations for these 10 heavy metals in groundwater in the study area is: Fe>Mn>Zn>Ni>Cu>Pb>>Sr>Co>Cd>Hg. The concentrations of Fe and Me ranged from 138.47 to 2187.81 μg/L and 0.45 to 135.68 μg/L, respectively, with the average concentrations of 857.41 μg/L and 13.9 μg/L. Results from single factor index and comprehensive pollution index evaluation methods indicated that the main heavy metals affecting groundwater quality in the study area were Fe, Pb, Zn, and Mn. Fe concentrations from 94.81% of groundwater sampling sites have exceeded the Class Ⅲ limit for groundwater quality standard (GB14848−2017). Fe, Mn, Co and Ni were derived from geological origins, Pb and Cd are derived from transportation and industrial origins, and Cu and Zn are derived from agricultural origins. The health risk of heavy metals in the groundwater was relatively low, and the non-carcinogenic risk caused by drinking water is the main pathway for groundwater in the study area. The order of health risk values is Fe>Pb>Mn>Co>Cu>Zn>Ni>Hg, and Fe were the main contributor to non-carcinogenic health risks.

       

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