ISSN 1009-6248CN 61-1149/P 双月刊

主管单位:中国地质调查局

主办单位:中国地质调查局西安地质调查中心
中国地质学会

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    不同浓度NaCl土壤–地下水蒸发积盐规律:(Ⅰ)物理实验

    Evaporation-Induced Salt Precipitation in Soil-Groundwater System under Different Concentrations of NaCl : (Ⅰ) Physical Experiment

    • 摘要: 土壤–地下水蒸发积盐在旱区广泛存在,但咸水与纯水的蒸发过程是否相同尚无统一认识,限制了人们对土壤–地下水蒸发积盐的深刻理解。为探明不同浓度NaCl的土壤–地下水蒸发积盐的阶段划分及其主控因素,本研究开展室内土柱实验,介质为石英砂,NaCl浓度分别为0 g/L、1 g/L、3 g/L、10 g/L、50 g/L,各浓度设两组平行实验,共10个土柱。实验历时43d,记录蒸发量,监测气温、表面温度和剖面温度,记录表面积盐变化,并测定表面盐层质量。结果表明:①纯水蒸发过程与前人研究一致,划分为Ⅰ恒速/高速(1~18 d)、Ⅱ过渡/减速(18~37 d)、Ⅲ扩散/低速阶段(37~43 d)3个阶段。(2)咸水蒸发也可划分为3个阶段,但各阶段的起始时间与强度随NaCl浓度变化;浓度越大,第Ⅰ阶段持续时间越短,第Ⅲ阶段越早开始,浓度为1 g/L、3 g/L、10 g/L和50 g/L的盐水蒸发第Ⅰ阶段持续时间分别为17 d、13 d、7 d和4 d,第Ⅲ阶段开始时间分别是第36 d、31 d、23 d、17 d;中–重度咸水(≥10 g/L)因表层盐壳覆盖更早进入第Ⅲ阶段,导致累积蒸发量降低;两组平行实验的累积蒸发量取平均值,纯水、1 g/L、3 g/L、10 g/L和50 g/L分别为228.25 cm、131.92 cm、117.45 cm、109.53 cm、29.16 cm。③蒸发主控因子随浓度与蒸发阶段变化:纯水、淡水(1 g/L)、轻度咸水(3 g/L)蒸发早期受温度主控;中度咸水(10 g/L)过渡期温度与基质势并重,溶质势开始增强并参与抑制;重度咸水(50 g/L)后期以溶质势为主。

       

      Abstract: Evaporation-induced salt precipitation in soil-groundwater system is widespread in arid regions. However, there is no consensus on whether the temporal stage division of evaporation for saline water is consistent with that for pure water, which limits a deeper understanding of evaporation-induced salt precipitation in soil-groundwater system. To clarify the stage division and the controlling factors of evaporation-induced salt precipitation under different NaCl concentrations, evaporation experiments were conducted with a Mariotte bottle providing a constant water supply. Quartz sand was used as the porous medium. Five concentrations were tested: 0, 1, 3, 10, and 50 g/L NaCl. Two parallel replicates were performed for each concentration, giving a total of ten soil columns. The experiment lasted 43 days. During the experiment, evaporation mass loss was recorded using an electronic balance; temperatures were monitored using temperature probes and a thermometer; and changes in surface salt features were photographed with an infrared camera. At the end of the experiment, the mass of the surface salt layer was measured. The results show that: (1) evaporation of pure water is consistent with previous studies and can be divided into three stages: Stage I, constant-rate or high-rate evaporation (days 1-18); Stage II, transitional or falling-rate evaporation (days 18-37); and Stage III, diffusion-limited or low-rate evaporation (days 37-43). (2) Evaporation of saline water can also be divided into three stages, but the onset time and intensity of each stage vary with NaCl concentration. With increasing concentration, Stage I becomes shorter and Stage III starts earlier. For 1, 3, 10, and 50 g/L, Stage I lasted 17, 13, 7 and 4 days, respectively, and Stage III started on days 36, 31, 23 and 17, respectively. For moderate to high salinity (≥10 g/L), earlier development of a surface salt crust led to an earlier transition to Stage III and reduced cumulative evaporation. By the end of the experiment, cumulative evaporation for the two replicates at 0, 1, 3, 10, and 50 g/L was 10581.28/12365.20 g, 6248.23/7013.64g, 6007.71/5800.05g, 5871.79/5139.17g, and 1306.78/1624.51g, respectively. (3) The controlling factors vary with both concentration and evaporation stage. In the early period, evaporation for 0, 1, and 3 g/L was mainly controlled by temperature. For 10 g/L, both temperature and water potential were important during the transitional stage, and the influence of solute effects became stronger and contributed to suppression. For 50 g/L, solute effects dominated in the later period.

       

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