ISSN 1009-6248CN 61-1149/P 双月刊

主管单位:中国地质调查局

主办单位:中国地质调查局西安地质调查中心
中国地质学会

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    东天山镜儿泉花岗伟晶岩型锂铍矿床成矿流体演化与稀有金属富集机制

    Characteristics of Ore-forming Fluids of the Jing'erquan Granitic Pegmatite-type Lithium-Beryllium Deposit in the Eastern Tianshan

    • 摘要: 富子晶流体包裹是伟晶岩熔-流体演化的关键载体,为揭示伟晶岩流体的起源、迁移、相态转变及其伴生的元素富集机制提供了最直接的证据。镜儿泉稀有金属矿床位于中亚造山带西段,是东天山最为典型的花岗伟晶岩型锂铍矿床,其成矿流体来源及演化特征仍不清楚。笔者对该矿床的伟晶岩中的流体包裹体开展了详细的岩相观察、激光拉曼光谱、显微测温及气相色谱和离子色谱等分析。结果表明,镜儿泉流体包裹体类型丰富、成矿流体整体表现为中低温(主要为240~380 ℃)、中低盐度(集中在1.0~5.5 wt%NaCleqv)、低密度(0.5~0.9 g/cm3)的特征,流体包裹体成分富含CO2、H2O、N2,还含有少量C2H2、CH4,相对富集F、Cl及碱金属阳离子。研究认为,镜儿泉锂铍矿成矿流体主要为岩浆来源,是花岗质岩浆在相对封闭环境下高度结晶分异演化的产物。花岗质岩浆不同阶段分异演化分别形成了以锂辉石和绿柱石为主的两条伟晶岩脉。成矿过程中流体性质发生了从中低温度、低盐度、低密度向低温、中低盐度、低密度的演化。其主要原因为,随着CO2和NaCl-H2O的温度、压力和溶解度的降低,CO2逐渐达到饱和并与成矿流体分离。在此过程中,CO2作为重要的载体,有利于锂的运移并富集成矿。此外,相对富集F、Cl及碱金属阳离子,其中F有利于与Li+、Be2+等稀有金属阳离子形成络合物或化合物的形式迁移并沉淀富集成矿。

       

      Abstract: Crystal-rich fluid inclusions serve as a crucial carrier in the evolution of pegmatitic melts-fluids, providing the most direct evidence for unraveling the origin, migration, phase transitions, and associated element enrichment mechanisms of pegmatitic fluids. The Jing'erquan rare metal deposit is a typical granite-pegmatite type lithium-beryllium deposit in the East Tianshan, western Central Asian Orogenic Belt. However, the source and evolutionary characteristics of its ore-forming fluids remain unclear. This study conducted detailed petrographic observations, along with laser Raman spectroscopy, microthermometry, gas chromatography, and ion chromatography analyses on fluid inclusions from pegmatites in this deposit. The results indicate that the fluid inclusions at Jing'erquan are diverse in type. They are generally characterized by moderate-low temperatures (mainly ranging from 240 ℃ to 380 ℃) and salinities (predominantly between 1.0 wt% NaCleqv and 5.5 wt% NaCleqv), as well as low densities (0.5~0.9 g/cm3). The fluid is rich in CO2, H2O, and N2, with minor amounts of C2H2 and CH4, and is relatively enriched in F, Cl, and alkali metal cations. This study proposes that the ore-forming fluids for the Jing'erquan Li-Be deposit were primarily magmatic in origin, resulting from the high fractional crystallization of granitic magma in a relatively closed environment. Two distinct pegmatite veins, dominated by spodumene and beryl, respectively, were formed during different stages of granitic magma differentiation. During the mineralization process, the fluid properties transitioned from moderate-low temperature-low salinity-low density to low temperature-moderate-low salinity-low density. The primary reason for this shift is that CO2 gradually reached saturation and separated from the ore-forming fluid, as the temperature, pressure, and solubility of CO2 and NaCl-H2O decreased. In this process, CO2 acted as an important carrier, facilitating the transportation and enrichment of lithium. Furthermore, the relative enrichment of F, Cl, and alkali metal cations played a significant role. Specifically, F was conducive to the formation of complexes or compounds with rare metal cations such as Li+ and Be2+, aiding their migration and subsequent precipitation and enrichment to form ore.

       

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