ISSN 1009-6248CN 61-1149/P 双月刊

主管单位:中国地质调查局

主办单位:中国地质调查局西安地质调查中心
中国地质学会

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    西昆仑造山带奥依塔格花岗岩体中褐帘石矿物学特征及其地质意义

    Mineralogical Characteristics and Geological Significance of Allanite from the Oytag Granitic Pluton in the West Kunlun Orogenic Belt

    • 摘要: 西昆仑造山带奥依塔格花岗岩体发育不同类型的褐帘石,为揭示岩浆–热液过程中稀土元素(REE)的地球化学行为提供了理想载体。通过背散射电子(BSE)图像观察与电子探针(EPMA)原位成分分析,笔者对奥依塔格岩体中褐帘石进行了系统的岩相学与矿物化学研究。根据BSE图像灰度、空间包裹关系及矿物共生组合,褐帘石可划分为3期。第一期褐帘石具有原生岩浆成因,在BSE图像下呈均匀的亮灰色,呈自形柱状单晶产出,常包含于斜长石或石英中,矿物组合简单。第二期褐帘石呈不均匀的暗灰色,以不规则形态沿第一期晶体的裂隙和边缘分布,局部发育蠕虫状显微纹理,常见绿帘石、萤石、磷钇矿、钙铒钇石–(Y)等交代矿物共生。第三期褐帘石BSE图像灰度最低,呈极暗色,常以极薄且不规则的反应边形式产出,共生有石英、钠长石。三期褐帘石的主量元素呈现连续的演化趋势,第一期褐帘石富集LREE(如Ce)和Fe、Mg,而Ca、Al含量极低;第二期褐帘石LREE和Fe、Mg显著降低,Si发生剧烈震荡,而Ca、Al显著升高,暗示其受到了富Ca-Al自交代热液的作用;第三期褐帘石LREE、Fe、Mg达到剖面最低值,而Ca、Al达到峰值,且Si趋于稳定,代表晚期流体的交代产物。笔者提出奥依塔格岩体经历了从岩浆结晶到多期流体的演化过程:①在岩浆期,褐帘石结晶并强烈富集LREE;②至热液交代期,富Cl但贫F的深部岩浆热液诱发早期褐帘石耦合溶解–再沉淀反应,导致LREE随流体向外流失,而M-HREE则因在贫络合剂流体中极低溶解度而原地过饱和沉淀,形成钙铒钇石–(Y)与磷钇矿;③最后弧后盆地海水的侵入则导致了褐帘石的开放体系蚀变。两类热液改造过程均伴随LREE的持续丢失,不同于与华南离子吸附型稀土成矿过程,指示西昆仑地区此类型成矿潜力较弱。

       

      Abstract: Different types of allanite occur in the Oytag granitic pluton of the West Kunlun orogenic belt, providing an ideal target for investigating the geochemical behavior of rare earth elements (REEs) during magmatic-hydrothermal processes. In this study, systematic petrographic and mineralogical investigations of allanite from the Oytag pluton were conducted through backscattered electron (BSE) imaging and in-situ electron probe microanalysis (EPMA). Based on BSE greyscale variations, spatial textural relationships, and mineral paragenesis, allanite can be subdivided into three stages. Stage 1 allanite is of magmatic origin, which appears as homogeneous bright grey domains in BSE images and occurs as euhedral prismatic crystals commonly enclosed within plagioclase or quartz, exhibiting a simple mineral assemblage. Stage 2 allanite is characterized by heterogeneous dark grey domains, irregularly distributed along fractures and grain margins of Stage 1 crystals, locally developing vermicular micro-textures and coexisting with metasomatic minerals such as epidote, fluorite, xenotime, and hellandite-(Y). Stage 3 allanite exhibits the lowest BSE greyscale, appearing as extremely dark, thin, and irregular reaction rims, and is associated with quartz, and albite. The major elements of allanite display a continuous evolution from Stage 1 to Stage 3. Stage 1 allanite is highly enriched in LREE (e.g., Ce), Fe, and Mg, with extremely low Ca and Al contents. In Stage 2 allanite, LREEs and Fe-Mg decrease significantly, accompanied by intense fluctuations in Si, whereas Ca and Al increase markedly, suggesting the influence of Ca-Al-rich deuteric fluids. Stage 3 allanite is characterized by the lowest LREEs, Fe, and Mg contents and highest Ca and Al contents, accompanied by stabilization of Si, indicating complete metasomatism by late-stage fluids. We propose that the Oytag pluton records a complete evolution from magmatic crystallization to multi-stage fluid alteration. (1) During the magmatic stage, primary allanite crystallized and became strongly enriched in LREE. (2) During the hydrothermal stage, Cl-rich but F-poor deep-seated magmatic hydrothermal fluids induced coupled dissolution–reprecipitation reactions of primary allanite, resulting in the outward loss of LREEs, whereas M-HREEs, due to their extremely low solubility in ligand-poor fluids, were precipitated in situ under local supersaturation to form hellandite-(Y) and xenotime. (3) The subsequent infiltration of back-arc basin seawater during Stage 3 led to the final open-system alteration of allanite. The continuous loss of LREEs during both hydrothermal processes differs from the formation process of regolith-hosted REE deposits in South China and reduces the metallogenic potential of this type of deposit in the West Kunlun region.

       

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