陕西汉中蛇纹石玉的矿物学及光谱学特征研究

杨眉; 何明跃; 王峰; 吴少坤; 李前志; 张碧瑶

doi:10.19751/j.cnki.61-1149/p.2021.04.011

陕西汉中蛇纹石玉的矿物学及光谱学特征研究

1. 中国地质大学(北京)科学研究院, 北京 100083;
2. 中国地质大学(北京)珠宝学院, 北京 100083;
3. 陕西地矿汉源玉业有限公司, 陕西汉中 723000

基金项目:

科技部国家科技资源共享平台“国家岩矿化石标本资源库”，陕西地矿集团有限公司地质科研专项资金项目“汉中金香玉宝石学特征及质量评价”（61201506290），中国地质调查局“地质信息产品体系研发与社会化服务”（DD20160353）项目联合资助。

详细信息

作者简介:
杨眉(1980-),硕士,助理研究员,主要从事矿物学、岩石学及矿床学研究。E-mail:yang_mei@yeah.net。

通讯作者:
何明跃(1963-),博士,教授,主要从事宝玉石学、矿物学、岩石学及矿床学研究。E-mail:hemy@cugb.edu.cn。

中图分类号: P575.4
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出版历程
- 收稿日期: 2020-07-19
- 修回日期: 2021-01-17
- 网络出版日期: 2022-07-28
- 发布日期: 2021-12-04

Mineralogical and Spectral Studies on the Serpentine Jade in Hanzhong,Shaanxi Province

1. Sciences Institute of China University of Geosciences, Beijing 100083, China;
2. Gemological Institute of China University of Geosciences, Beijing 100083, China;
3. Shaanxi Mine in Hanyuan Jade Industry Co., Ltd., Hanzhong 723000, Shaanxi, China

摘要

摘要: 陕西汉中蛇纹石玉质地细腻温润，颜色浓郁均匀，呈独特的黄色至深棕色色调，是蛇纹石质玉石中的优质品种。X射线荧光光谱分析表明，玉石主要化学成分为SiO₂（42.90%~44.62%）和MgO （43.03%~44.10%）。X射线粉晶衍射、拉曼光谱和红外光谱分析显示，该蛇纹石玉的矿物组成为1T型利蛇纹石，玉石裂隙中普遍发育的石棉为正纤蛇纹石。
- 汉中 /
- 蛇纹石玉 /
- 1T型利蛇纹石 /
- 拉曼光谱 /
- 红外光谱
Abstract: The serpentine jade, produced in Hanzhong, Shaanxi province, has a fine delicate and moist quality. It appears to be a unique yellow to dark brown colour. XRF analysis shows that SiO₂(42.90%~44.62%) and MgO(43.03%~44.10%) are the main chemical composition of the jade. XRD analysis reveals that the mineral composition of the serpentine jade is 1T-lizardite; in jade cracks the commonly developed asbestos is orthochrysotile.
- Hanzhong /
- Shaanxi province /
- serpentine jade /
- 1T-lizardite /
- FT-Raman spectrum

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参考文献(32)

张蓓丽.系统宝石学[M]. 北京:地质出版社, 2006.

ZHANG Beili.Systematic Gemmology[M]. Beijing:Geology Press, 2006.

杨剑洲, 龚晶晶, 高健翁, 等.北山造山带白云山蛇绿岩地幔橄榄岩成因及形成环境[J]. 西北地质, 2019, 52(3):1-13.

YANG Jianzhou, GONG Jingjing, GAO Jianweng, et al. Petrogenesis and Geotectonic Setting of Mantle Peridotites from the Baiyunshan Ophiolite in Beishan Orogen[J]. Northwestern Geology, 2019, 52(3):1-13.

刘刚, 苏山立. 蛇纹石族矿物X射线衍射谱鉴定特征及区别[J]. 中国非金属矿工业导刊, 1986, (2):36-42.

LIU Gang, SU Shanli.Characteristics and Differences of X-Ray Diffraction Spectra of Serpentine Minerals[J]. China Non-Metallic Mining Industry Herald, 1986, (2):36-42.

王永亚, 顾冬红, 干福熹.中国蓝田玉的成分、物相及结构分析[J]. 岩石矿物学杂志, 2011, 30(02):325-332.

WANG Yongya, GU Donghong, GAN Fuxi.An analysis of mineral structure and chemical composition of China's Lantian Jade[J].Acta Petrologica et Mineralogica, 2011, 30(02):325-332.

王永亚, 干福熹.广西陆川蛇纹石玉的岩相结构及成矿机理[J]. 岩矿测试, 2012, 31(05):788-793.

WANG Yongya, GAN Fuxi.Mineral Structure and Mineralization Mechanism of Serpentine Jade from Luchuan, Guangxi Province[J].Rock And Mineral Aanlysis, 2012, 31(05):788-793.

刘志勇, 干福熹, 承焕生, 等.辽宁岫岩玉的岩相结构和无损分析研究[J]. 岩石学报, 2009, 25(05):1281-1287.

LIU Zhiyong, GAN Fuxi, CHENG Huansheng, et al. Mineral structure and nondestructive analysis of Xiuyan Jade from Liaoning Province[J]. Aeta Petrologica Sinica, 2009, 25(05):1281-1287.

甘保平, 赖绍聪, 秦江锋.米仓山新民角闪辉长岩地球化学特征及其构造意义[J]. 岩石矿物学杂志, 2016, 35(2):213-228, 167.

GAN Baoping, LAI Shaocong, QIN Jiangfeng.Geochemistry of the Bojite From the Xinmin Area, Micang Mountain[J]. Acta Petrologica et Mineralogica, 2016, 35(2):213-228, 167.

薛国栋, 何政伟, 向启荣, 等.南米仓山变质岩变质时代及地质意义[J]. 四川地质学报, 2018, 38(2):202-207+211.

XUE Guodong, HE Zhengwei, XIANG Qirong, et al. Metamorphic Age and Geological Significance of Metamorphic Rocks in Nanmeicang Mountain[J]. Acta Geologica Sichuan, 2018, 38(2):202-207+211.

张茜, 董云鹏, 杨晨, 等.米仓山隆升时代的沉积学制约[J]. 西北地质, 2010, 43(3):12-19

ZHANG Qian, DONG Yunpeng, YANG Chen, et al. Sedimentological Restriction During the Uplift Period in Micangshan[J]. Northwestern Geology, 2010, 43(3):12-19.

张昕, 吴才来, 陈红杰.秦岭南召岩体中花岗岩脉的锆石U-Pb定年:对燕山期构造环境的约束[J]. 中国地质, 2017, 44(5):938-958.

ZHANG Xin, WU Cailai, CHEN Hongjie.The U-Pb zircon dating of the granite dike in Nanzhao pluton and it's constraints on tectonic setting in Yanshanian[J]. Geology in China, 2017, 44(5):938-958.

黄瑢, 赖潇静, 秦善, 等.同步辐射X 射线衍射研究利蛇纹石的压缩性[J]. 核技术, 2012, 35(11):801-805.

HUANG Rong, LAI Xiaojing, QIN Shan, et al. Synchrotron Radiation X-Ray Diffraction Studies the Compressibility of Serpentine[J]. Nuclear Techniques, 2012, 35(11):801-805.

Mellini M, Trommsdorff V, Compagnoni R.Antigorite Polysomatism:Behaviour During Progressive Metamorphism[J]. Contrib.Mineral.Petrol, 1987, 97:147-155.

Kloprogge J T, Frost R L, Rintoul L.Single Crystal Raman Microscopic Study of the Asbestos Mineral Chrysotile[J]. Physical Chemistry Chemical Physics, 1999, 1(10):2559-2564.

Etienne B, Marco S A, Francesco M, et al. First-Principles Calculation of the Infrared Spectrum of Lizardite[J]. American Mineralogist, 2002, 87(10):1286-1290.

Auzende A, Devouard B, Guillots.Serpentinites From Central Cuba:Petrology and HRTEM Study[J]. Eur J Mineral, 2002, 14:905-914.

Caterina R, Daniela G, Elena B.Characterization of Chrysotile, Antigorite and Lizardite by FT-Raman Spectroscopy[J]. The Canadian Mineralogist, 2003, 41(4):883-890.

Mauro P, Yves N, Marco B, et al. The Vibrational Spectrum of Lizardite-1T[Mg₃Si₂O₅(OH)₄] at the Γ Point:A Contribution From an ab Initio Periodic B3LYP Calculation.[J]. American Mineralogist, 2009, 94(7):986-994.

Trittschack R, Grobety B, Koch-Muller M.In Situ High-Temperature Raman and FTIR Spectroscopy of the Phase Transformation of Lizardite[J]. American Mineralogist, 2012, 97:1965-1976.

Petriglieri J R, Salvioli-Mariani E, Mantovani L, et al. Micro-Raman Mapping of the Polymorphs of Serpentine[J]. Journal of Raman Spectroscopy, 2015, 46(10):953-958.

Marquardt H, Speziale S, KochmüLler M, et al. Structural Insights and Elasticity of Single-Crystal Antigorite From High-Pressure Raman and Brillouin Spectroscopy Measured in the (010) Plane[J]. American Mineralogist, 2015, 100(8-9):1932-1939.

Farmer V C. The Infrared Spectra of Minerals[M]. Adlard & Son Ltd., At the Bartholomew Press, 1974.

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