利用MC-ICP-MS测定铁同位素方法综述

霍金晶; 韩延兵

doi:10.19751/j.cnki.61-1149/p.2021.04.024

利用MC-ICP-MS测定铁同位素方法综述

霍金晶¹,
韩延兵^2, ,

1. 合肥工业大学资源与环境工程学院, 安徽合肥 230009;
2. 中国地质调查局西安地质调查中心, 西北地质科技创新中心, 陕西西安 710054

基金项目:

国家自然科学基金项目“大别苏鲁造山带超高压变质大理岩及其包裹榴辉岩的Mg同位素地球化学”（41703006），中央高校基本科研业务费专项项目“大陆风化过程中的K同位素地球化学行为研究”（JZ2019HGTB0071）。

详细信息

作者简介:
霍金晶(1990-),女,河北唐山人,理学硕士研究生。E-mail:huojinjing90@163.com。

通讯作者:
韩延兵(1968-),男,本科,高级工程师。E-mail:1434136886@qq.com。

中图分类号: P629
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出版历程
- 收稿日期: 2021-01-14
- 修回日期: 2021-03-29
- 网络出版日期: 2022-07-28
- 发布日期: 2021-12-04

A Review of MC-ICP-MS Fe Isotope Analytical Methods

HUO Jinjing¹,
HAN Yanbing^2, ,

1. School of Resources and Environmental engineering, Hefei University of Technology, Hefei 230009, Anhui, China;
2. Xi'an Center of China Geological Survey, Northwest China Center for Geoscience Innovation, Xi'an 710054, Shaanxi, China

摘要

摘要: 多接收电感耦合等离子体质谱（MC-ICP-MS）的应用已在金属稳定同位素分析方法上取得重大突破，促进了金属稳定同位素地球化学的快速发展。铁同位素作为一种新的同位素示踪体系，已广泛应用于主要的地球科学及其分支学科的研究中。目前，MC-ICP-MS对铁同位素的日常测定精度可以达到±0.03‰，但化学纯化和仪器分馏引起的质量偏差很容易引起较大的分析误差。因此，准确获取天然样品的铁同位素组成数据仍然是一个挑战。笔者系统回顾了铁同位素分析技术的发展，详细描述了铁同位素分析过程，包括化学纯化过程、仪器质量歧视校正和基质效应的规避等。
- 铁同位素 /
- 多接收电感耦合等离子体质谱 /
- 质量歧视校正 /
- 同位素分馏 /
- 基质效应
Abstract: The use of multi-collector inductively coupled plasma mass spectrometry (MC-ICP-MS) paved the way in the stable isotope analysis of metals, promoting the rapid development of non-traditional stable isotope geochemistry, among which, Fe isotope has received the greatest attention. This surge of study has been fueled largely by the redox-sensitive nature of iron as well as its availability in life. The research on the distribution and isotopic compositions of iron has covered almost all sub-branches of earth science, ranging from biochemistry to geochemistry. The MC-ICP-MS instrument has been demonstrated to be very efficient in determining trace element compositions in a wide variety of applications. However, many questions, such as chemical purification, mass bias correction and efficiently avoid of matrix effects, remain challenging.
- Fe isotope /
- MC-ICP-MS /
- mass bias calibration /
- isotope fractionation /
- matrix effects

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