甘肃北山红山铁矿区硅质岩地球化学特征及其成因意义
Geochemical Characteristics of Chert of Hongshan Iron Deposit in Gansu Province and Its Petrogenic Significance
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摘要: 甘肃北山地区红山铁矿区硅质岩与铁矿体紧密伴生,且有些硅质岩本身就是铁矿石.常量元素分析表明:硅质岩普遍具有高Si、高Fe、低Al特征,K2O含量普遍高于Na2O,且Fe/Ti值为57.14~218.74,(Fe+Mn)/Ti值为57.54~224.16,Al/(Al+Fe+Mn)值为0.05~0.14,均符合热水沉积硅质岩的特征,但存在少量陆源物质介入.稀土微量元素分析表明:硅质岩大部分微量元素相对于克拉克值亏损,稀土元素总量低,经北美页岩标准化后,Ce异常明显或微明显,Eu呈现明显的正异常,重稀土相对轻稀土富集;δCe值为0.93~1.05,平均为0.99;La/Ce值为0.43~0.49,平均为0.44,更接近于大陆边缘硅质岩的特征.综合以上地球化学特征,硅质岩具有明显的热水沉积成因属性,同时有陆源组分的加入,进而得出红山铁矿为与热水沉积成因有关的铁矿床,当时形成环境为大陆边缘环境.Abstract: The chert from Hongshan iron deposit is closely associated with the iron ore body, and some cherts are iron ores themself. Chemical analysis of the chert shows that it generally has the features of high content of Si and Fe, low content of Al, and higher content of K2O than Na2O, and the ratio of Fe/Ti is between 57.14-218.74, (Fe+Mn)/Ti is between 57.54-224.16, Al/(Al+Fe+Mn) is between 0.05-0.14, which are all according with the features of hydrothermal sedimentary chert, but with little terrigenous materials. Trace element analysis of the chert shows that most of the trace elements are lower than the Clarke value and the total REE is lower. Normalized by the North American shale, HREE is richer than LREE, and the geochemical characteristics of the chert indicate that they are hydrothermally sedimentary origin, but with existence of certain continental sources. So it can be concluded that the Hongshan iron deposit is associated with hydrothermal deposite with terrigenous materials and it was formed in the environment of continental margin.