The Types of Rare and Disperse Scandium Deposits and Prospecting Potential
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摘要: Sc是一种典型的稀散元素,常类质同象进入镁铁质矿物中。自然界中罕见钪的富集体。Sc主要是从铝土矿、钛铁矿、磷块岩、黑钨矿、锡石等矿石中作为伴生元素加以回收。近几年,随着对复杂硅酸盐矿物Sc浸出试验的研究,Sc元素也可从富Sc的基性-超基性岩体(Sc2O3>50×10-6)中提取。主要富Sc矿物有单斜辉石、角闪石。云南二台坡岩体源区可能具有富Sc的特性,在岩浆结晶早期大量进入镁铁质硅酸盐矿物,形成钪的独立矿床(Sc2O3=66.08×10-6)。这类矿床在国内外还属首例,其发现扩大了独立钪矿床类型,对寻找新型钪矿具有重要的指导意义。Abstract: Scandium is a typical rare and disperse element, and distributes widely in trace amounts in rocks consisting of ferromagnesian minerals. Scandium-concentrated ores are rare in nature, thus the scandium was mainly recovered as a by-product from the ores of monohydrallite, ilmenite, phosphorite, wolframite, tinstone etc. Recently, with the analysis and study on the enrichment experiment of the complex silicate mineral containing scandium, scandium can be extracted from mafic-ultramafic scandium-rich ore bodies containing scandium oxide more than 50×10-6. The ores of scandium are mainly consisted of clinopyroxene, amphibole. The origin of Ertaipo intrusion is of high scandium, which enters the ferromagnesian minerals during the early fractional crystallization largely to form the new independent deposit, whose Sc2O3 is equal to 66.08×10-6. This kind of deposit is firstly discovered at home and abroad, enlarging the new types of independent deposit and having great significance to the prospecting of Scandium deposit.
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Keywords:
- scandium /
- ore deposit /
- mafic-ultramafic ore body /
- Ertaipo /
- Mouding of Yunnan
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杨军臣, 王凤玲, 李德胜, 等.铝土矿中伴生稀有稀土元素赋存状态及走向查定[J].矿冶, 2004, 2(13):89-92. Yang Junchen, Wang Fengling, Li Desheng, et al.Investigation on occurrence and trend of rare and rare-earth elements associated in bauxite[J].Mining&metallurgy, 2004, 13(2):89-93.
匡敬忠, 肖坤明, 曾军龙.从铝土矿磷矿及铌钽矿中综合回收稀土的研究进展[J].稀土, 2012, 1(33):81-85. Kuang Jingzhong, Xiao Kunming, Zeng Junlong.Progress in Research on Rare Earth Recovery fron Bauxite, Phosphorite and Nb-Ta Minerals[J].Chinese Rare Earths, 2012, 33(1):81-85.
张玉学.分散元素钪的矿床类型与研究前景[J].地质地球化学, 1997, 4:93-97. Zhang Yuxue.Types of Sc deposites and research prospects[J].Geology-Geochemistry.1997, 4:93-97.
龙志奇, 王良士, 黄小卫, 等.磷矿中微量稀土提取技术研究进展[J].稀有金属, 2009, 3(33):434-441. Long Zhiqi, Wang Liangshi, Huang Xiaowei et al. Proress in Extraction Technique for Trace Rare Earths from Phosphorite[J].Chin ese journa l of rare metlas 宋万灏, 王桂芳, 宋学全.磷矿石中稀土元素赋存状态的研究[J].地质实验室, 1997, 2(13):123-125. Song Wanhao, Wang Guifang, Song Xuequan. Research on the state of rare earth elements in phosphates[J]. Geological laboratory, 1997, 2(13):123-125.
王华, 洪业汤, 朱咏煊, 等.黄磷生产中的稀土元素分布[J].稀土, 2002, 4(23):25-28. Wang Hua, Hong Yetang, Zhu Yongxuan, et al., Rare Earth Distribution during Production of Yellow Phosphorus[J].Chinese Rare Earths, 2002, 4(23):25-28.
刘水庚. 试论江西钨选矿中钪元素的走向[J].有色金属(选矿部分), 1989, 6:5-10. Liu Shuigeng. Research on the trend during the scandium dressing in tungsten ore, Jiangxi[J]. Non-ferrous metals(concentration), 1989, 6:5-10.
吕宪俊, 程系翱, 周国华. 攀枝花铁矿石中钪的赋存状态研究[J]. 矿冶工程, 1992, 4(12):35-38. LÜ Xianjun, Cheng Xiao, Zhou Guohua. Occurrence state of scandium in Panzhihua iron ore[J]. Mining and Met-allurgical Engineering, 1992, 12(4): 35-39(in Chinese with English abstract).
王彦斌, 王登红, 韩娟, 等. 湖南益将稀土-钪矿的石英闪长岩锆石U-Pb定年和Hf同位素特征:湘南加里东期岩浆活动的年代学证据[J].中国地质.2010, 37(4):1062-1070. Wang Yanbin, Wang Denghong, Han Juan, et al. U-Pb dating and Hf isotopic character-istics of zircons from quartz-diorite in the Yijiang REE-Sc deposit, Rucheng County, Hunan: constraints on the timing of Caledonian magmatic activity in South China[J]. Geology in China, 2010, 37(4): 1062-1070(in Chinese with English abstract). 刘英俊, 曹励明, 李兆麟, 等. 元素地球化学[M]. 北京:科学出版社, 1986. Liu Yingjun, Cao Liming, Li Zhaolin, et al. Element geochemistry[M].Sciemce Press. 1986.
朱敏杰, 沈春英, 丘泰. 稀有元素钪的研究现状[J]. 材料导报, 2006, 20(S1): 379-381. Hu MinJie, Shen Chunying, Qiu Tai.Research State of Lanthanon: Scandium[J]. Material Guide, 2006, 20(S1): 379-381(in Chinese with English abstract).
徐刚. 我国钪资源开发利用的战略思考. 中国选矿技术网, 2007, 8-14. http://www.mining120.com/html/0708/ 20070814_10150.asp.2007-8-14.
XU Gang. Strategy on develo pment and utilization of scan-dium resources of China.Mining120.com, http://www.mining120.com/html/0708/20070814_10150.asp.2007-8-14.
Α. Д. Капенов, Р. М. Риберцал著. 陈云祥译. СКАНДИЙ(钪)[M]. 北京工业出版社. 1962. Α. Д. Капенов, Р. М. Риберцал (write). Chen Yunxiang (translte). СКАНДИЙ[M]. China Industry Press.1962:5-22.
谭俊峰. 云南复杂硅酸盐含钪矿物选矿-浸出试验研究[D]. 昆明:昆明理工大学, 2012. Tan Junfeng. Research on the Experiments of Scandium dressing and leaching from complex silicate ore with scandium[D]. Kunming:Kunming University of Science and Technology, 2012.
马升峰. 白云鄂博稀选尾矿中钪的提取工艺研究[D]. 内蒙古:内蒙古大学, 2012. Bai Shengfeng. Study on extraction technology of scandium form the Bayanobo tailings[D]. Inner Mongolia University, 2012.
张涛石. 论含钪矿床[J]. 中国地质科学院院报, 1980, 1(1):89-96. Zhang Taoshi. On the deposit containing scandium[J]. Chinese Academy of Geological Sciences. 1980, 1(1):89-96.
姬琦, 张世涛, 邹国富, 等. 元谋地区超基性岩浆型铂钯矿成矿作用探讨[J]. 地质找矿论丛, 2011, 4(26):393-398. Qi Ji, Zhang Shitao, Zou Guofu, et al. Discussion on ultra-basic magmatic Pt -Pd mineralization in Yuanmou area[J]. Contributions to geology and mineral resources research, 2011, 4(26):393-398.
云南有色楚雄勘察院. 云南牟定县二台坡基性超基性岩详查报告[R]. 2009, 12. 吴利仁. 论中国基性岩、超基性岩的成矿专属性[J]. 地质科学. 1963, 1:29-41. Wu Liren. Metallogenic specialization of basic and ultrabasic rocks, China[J].Geoscience, 1963, 1:29-41.
朱智华. 云南牟定县二台坡岩体中钪的发现及其意义[J]. 云南地质. 2010, 3(29):235-244. Zhu Zhihua. The discovery and significance of Sc in Er-taipo intrusion of Mouding, Yunnan[J]. Yunnan Geology, 2010, 29(3): 235-244(in Chinese with English abstract).
郭远生, 曾普胜, 郭欣, 等. 钪的有关问题暨滇中地区基性-超基性岩含钪性研究[J]. 地球学报. 2012, 5(33):745-754. Guo Yuansheng, Zeng Pusheng, Guo Xin, et al., Some Problems concerning Scandium and Scandium-bearing Potential of the Mafic-ultramafic Intrusions in Central Yunnan Province[J]. Acta Geoscientica Sinica, 2012, 5(33):745-754.
夏林圻, 徐学义, 李向民, 等. 亚洲3个大火成岩省(峨眉山西伯利亚、德干)对比研究[J].西北地质, 2012, 45(2):1-26. Xia Linqi, Xu Xueyi, Li Xiangmin, et al., Comparison of three large igneous province (Emeishan, Siberia, Deccan ) in Asia[J].Northwestern geology, 2012, 45(2):1-26.
沈发奎. 攀西裂谷岩浆系列[J]. 矿物岩石, 1986, 6(3): 39-50. Shen Fakui. Magmatic series of Pan-Xi Rift[J]. Minerals and Rocks, 1986, 6(3): 39-50(in Chinese with English abstract).
姚家栋. 四川攀西地区阿拉斯加型岩体的发现及其地质意义[J]. 中国地质, 1987, (5): 25-26. Yao Jiadong. Discovery of Alaska-type intrusions in Pan-Xi area, Sichuan and their geological significances[J]. Geology in China, 1987, (5): 25-26(in Chinese). 刘红英, 夏斌, 张玉泉. 攀西裂谷带内超基性碱性岩和层状辉长岩40Ar/39Ar年龄: 以鸡街大向坪和太和岩体为例[J]. 地质论评, 2004, 50(2): 175-179. Liu Hongying, Xia Bin, Zhang Yuquan. 40Ar/39Ar Ages of the ultrabasic alklic rock and layered gabbro in Panzhi-hua-Xichang rift zone: examples from the Jijie, Daxiangping and Taihe pluton[J]. Geological Review, 2004, 50(2): 175-179(in Chinese with English abstract).
张招崇. 关于峨眉山大火成岩省一些重要问题的讨论[J]. 中国地质, 2009, 36(3): 634-646. Zhang Zhaochong. A discussion on some important prob-lems concerning the Emeishan large igneous province[J]. Geology in China, 2009, 36(3): 634-646(in Chinese with English ab-stract).
马言胜, 陶琰, 钟宏, 等. 四川阿布郎当超镁铁质侵入体成岩机制的地球化学约束[J]. 岩石学报, 2009, (5): 1146-1158. Ma Yansheng, Tao Yan, Zhong Hong, et al.Geochemical constraints on the petrogenesis of the Abulangdang ultramafic intrusion, Sichuan Province, China[J]. Acta Petrologica Sinica, 2009, 25(5): 1146-1158(in Chi-nese with English abstract).
姜常义, 凌锦兰, 赵彦锋, 等. 镁铁质-超镁铁质岩体含矿性评价指标体系——应用于寻找岩浆硫化物矿床[J].西北地质, 2012, 45(4):51-60. Jiang Changyi, Ling Jinlan, Zhao Yanfeng, et al., Ore-bearing Potential Evaluation Index System of Mafic and Ultramafic Intrusions-Used to Search for Magmatic Sulfide Deposits[J].Northwestern geology, 2012, 45(4):51-60.
王生伟, 孙晓明, 史贵勇, 等.云南金宝山和白马寨铜镍硫化物矿床铂族元素(PGE)地球化学的差异及其成因意义[J].地质学报, 2007, 81(1):93-108. Wang Shengwei, Sun Xiaoming, Shi Guiyong, et al. Distinction of Platinum Group Elements(PGE)Geochemistry between the Jinbaoshan and Baimazhai Magmatic Sulfide Deposits in Yunnan Province, China, and Its Implication for Ore Genesis[J]. Acta geologica sinica, 2007, 81(1):93-108.
陶琰, 高振敏, 罗泰义, 等. 云南金宝山超镁铁岩原始岩浆成分反演[J].岩石学报, 2002, 18(1):70-82 Tao Yan, Gao Zhenmin, Luo Taiyi, et al. Inversion of Primary magma com-position for Jinbaoshan ultramafic intrusion, Yunnan[J]. Acta Petrologica Sinica, 2002, 18(1): 70-82(in Chinese with English ab-stract). 陶琰, 高振敏, 罗泰义, 等. 金宝山岩体铂族元素特征及成因意义[J]. 矿物岩石地球化学通报, 2004, 23(1): 28-31. Tao Yan, Gao Zhenmin, Luo Taiyi, et al., PGE in Jinbaoshan Intrusion:Possible Evidence of Mantle Plume Origin[J]. Bulletin of Mineralogy, Petrology and Geochemistry, 2004, 23(1): 28-31(in Chinese with English abstract). 陶琰, 罗泰义, 高振敏, 等. 西南暗色岩铜镍硫化物矿化岩体与峨眉山玄武岩的关系以云南金宝山岩体为例[J]. 地质论评, 2006, 50(1): 9-15. Tao Yan, Luo Taiyi, Gao Zhenmin, et al. The rela-tion between Emeishan continental flood basalts and Cu-Ni-PGE deposits of southwestern China trap: a case study on Jinbaoshan mafic-ultramafic intrusion, Yunnan[J]. Geo-logical Review, 2006, 50(1): 9-15(in Ch inese with English abstract). 陶琰, 胡瑞忠, 漆亮, 等 四川力马河镁铁-超镁铁质岩体的地球化学特征及成岩成矿分析[J]. 岩石学报, 2007a, 23(11): 2785-2800. Tao Yan, Hu Ruizhong, Qi Liang, et al. Geochemical characteristics and metallogenesis of the Limahe mafic-ultramafic intrusion, Sichuan[J]. Acta Petrologica Sinica, 2007a, 23(11): 2785-2800(in Chinese with English abstract). 陶琰, 朱丹, 高振敏, 等. 云南金宝山铂钯矿Pd赋存状态的补充研究[J]. 矿物学报, 2007b, 27(3-4): 262-264. Tao Yan, Zhu Dan, Gao Zhenmin, et al. An additional study on the Pd-occurrence states in the Jinbaoshan Pt-Pd deposit[J]. Acta Mineralogica Sinica, . 2007b, 27(3-4): 262-264(in Chinese with Eng-lish abstract). 陶琰, 马言胜, 苗来成, 等. 云南金宝山超镁铁岩体锆石SHRIMP年龄[J]. 科学通报, 2008, 53(22): 2828-2832. Tao Yan, Ma Yansheng, Miao Laicheng, et al. SHRIMP dating of zircon from Jinbaoshan ultramafic intrusion in Yunnan, SW China[J]. Bulletin of Science in China, 2008, 53(22): 2828-2832(in Chinese). 陶琰, 朱飞霖, 于宋月, 等. 四川会理小关河地区岩浆硫化物矿床成矿系统[J]. 矿物学报, 2011, (S1): 174. Tao Yan, Zhu Feixia, Yu Songyue, et al. Metallogenic system of the magmatic sulfide ore deposits in Xiaoguanhe district, Huili, Sichuan Province[J]. Mineralogica Acta, 2011, (S1): 174(in Chinese). 马言胜, 陶琰, 钟宏, 等. 四川阿布郎当超镁铁质侵入体成岩机制的地球化学约束[J]. 岩石学报, 2009, (5): 1146-1158. Ma Yansheng, Tao Yan, Zhong Hong, et al. Geochemical constraints on the petrogenesis of the Abulangdang ultramafic intrusion, Sichuan Province, China[J]. Acta Petrologica Sinica, 2009, 25(5): 1146-1158(in Chi-nese with English abstract). 战新志. 金宝山铂矿床硫化物共生组合的演化及铜、钴、镍、铂族元素成矿阶段[J].地球化学, 1992, (1):95-100. Zhan Xinzhi. Evolution of paragenetic sulfide assemblages and Cu-Co-Pt mineralization stages of Jinbaoshan platinum deposit[J]. Geochemistry, 1992, (1):95-100.
张旗, 李达周, 张魁武. 对云南阿拉斯加型基性-超基性岩及其地质-找矿意义的初步认识[J]. 云南地质, 1984, 3(3): 245-255. Zhang Qi, Li Dazhou, Zhang Kuiwu. Preliminary study on Alaska-type basic-ultrabasic rocks in Yunnan and their ge-ological-prospecting significance[J]. Yunnan Geology, 1984, 3(3): 245-255(in Chinese). 姚家栋. 四川攀西地区阿拉斯加型岩体的发现及其地质意义[J]. 中国地质, 1987, (5): 25-26. Yao Jiadong. Discovery of Alaska-type intrusions in Pan-Xi area, Sichuan and their geological significances[J]. Geology in China, 1987, (5): 25-26(in Chinese). Wang C Y, Zhou M F. Genesis of the Permian Baimazhaimagmatic Ni-Cu-(PGE) sulfide deposit, Yunnan, SW China[J].Mineralium Deposita, 2006a, 41(8): 771-783.
Wang C Y, Zhou M F, Keays R R. Geochemical con-straints on the origin of the Permian Baimazhai ma-fic-ultramafic intrusion, SW China[J]. Contributions to Min-eralogy and Petrology, 2006b, 152(3): 309-321.
朱丹, 徐义刚, 罗泰义, 等. 峨眉山玄武岩的输送通道:云南元谋朱布岩体[J]. 矿物学报, 2007, 3/4(27):273-280. Zhu dan, Xu Yigang, Luo Taiyi, et al.Conduit of the Emeishan basalts: the Zhubu mafic-ultramafic intrusion in the Yuanmou area of Yunnan province, china[J]. Acta mineralogical sinica, 2007, 3/4(27):273-280.
黎彤. 岩石圈及其结构层的元素丰度[J]. 地质学报, 1985, 3:219-227. Li Tong. The abundance of chemical elements in the lithosphere and its structural layers[J]. Acta geologica sinica.1985, 3:219-227.
Борисенко Л.Ф.Генетические типы месторождений скандия[J]. Лцшолоеця ц попезые цскопаемые, 1988, (4):82-90 Cotton F A, Wilkinson G, Bochmann M, et al. Advanced Inorganic Chemistry[M]. 5th ed. New York: Wiley Inter Science. 1988. Hedrick, J. B. Scandium. Mineral Commodity Summaries[J]. U. S. Geological Survey, 2010b:140-142.
Wang Weiwei, Pranolo Yoko, Cheng Chu Yong. Metallurgical processes for scandium recovery from various resources: A review[J]. Hydrometallurgy. 2011, 108:100-108.
V. M. Goldschmidt. Geochemistry[M]. Oxford at the Clarendon Press. 1959.
Щербина В. В.. Факторы, опредепыощие геохимическое расцределение скандия Геохцмня[J]. 1959, 8.
Guo, G., Chen, Y., Li, Y.Solvent extraction of scandium from wolframite residue[J]. JOM, 1988, 40 (7), 28-31. Hedrick, J. B., Rare Earth. Minerals Yearbook[M]. 2010b. U. S. Geological Survey.
Irvine, J. T. S., Politova, T., Zakowsky, N., et al. Scandia-Zirconia Electrolytes and Electrodes for SOFCS[J]. In: Proceedings of the NATO Advanced Research Workshop on Fuel Cell Technologies: State and Perspectives[J]. Kyiv, Ukraine, 2004, 35-47.
E. S. Larsen and Montgomery A., Sterrettite, a new mineral from Fairfield[J]. Utah. American mineralogist, 1940, 25(8): 513-518.
Xu, S., Li, S. Review of the extractive metallurgy of scandium in China (1978-1991)[J]. Hydrometallurgy, 1996, 42, 337-343. Munnoch, S., Worstall, T. Scandiu m. Report of Minor metals Trade Association[M], 2003.
Desc hamps, Y., 2003. Scandium, In Report of BRGM (in French). http://www. mineralinfo. org/Substance/Scandium/Sc. pdf.
Zhou M F, Robinson P T, Lesher C M, et al. Geochemistry, Petrogenesis and Met-allogenesis of the Panzhihua Gabbroic Layered Intrusion and Associated Fe-Ti-V-Oxide Deposits, Sichuan Province, SW China[J]. Journal of Petrology, 2005, 46(11): 2253-2280. Zhou M F, Malpas J, Song X Y, et al. A temporal link between the Emeishan large igneous province (SW China) and the end-Guadalupian mass extinction[J]. Earth and Planetary Science Letters. 2002, 196(3-4): 113-122.
Sun S S., McDougal W F. Chemical and isotope systematic of oceanic basalts: Implication for mantle composition and processes. In: Saunders AD and Norry MJ (eds). Magmatism in the Ocean Basins[J]. Geol. Soc. Spec. Publ., 1989, 42:313-315.
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