The Occurrence State and Restraint Factors of Helium-produced Elements (U, Th) in the Granites from the Southern Margin of Weihe Basin: Evidences from Huashan Complex
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摘要: 花岗岩在氦气生成、储存和释放机理方面已经取得了诸多进展,但对其中U、Th生氦元素的赋存状态及相应的制约因素仍缺乏系统研究。渭河盆地南缘分布的巨量花岗质岩基被认为是盆地重要的氦源岩。笔者以渭河盆地南缘代表性的华山复式岩体为研究对象,对岩体样品进行了电子探针定性分析和副矿物组合定量分析。分析结果显示,样品中放射性U、Th元素主要赋存于锆石、榍石、磷灰石之中;燕山期侵入体中Th含量主要受控于锆石,U含量由锆石和褐帘石联合制约;而印支期侵入体中Th、U含量主要受控于锆石和榍石及少量钍石。对放射性U、Th含量和部分熔融模拟联合研究表明,基底太华群不均一的成分及其部分熔融程度可能是样品中放射性U、Th含量的根本制约因素。Abstract: Granites have been constantly concerned and much progress has been achieved on the production, storage and release of helium. However, there is lack of further study about the occurrence state, restraint factors and effective assessment of helium-produced elements (U, Th) in the granites when granites had been generated. A large number of granitic batholiths, located at the southern margin of Weihe basin, were considered to be the crucial source of helium. This study focused on the representative Huashan granitic batholith. The EMPA analyses and identifications for placer minerals showed that U and Th were mainly stored in zircons, titanites and apatites from Huashan granitic batholith. The Th content was mostly depended on the content of zircon and U content was controlled by zircon and allanite in the Yanshanian pluton, while Th and U content were dominantly related to zircon, titanite and minor thorite in the Indonian pluton. Meanwhile, the contents of U and Th in the samples mentioned above were determined and synthetical study suggested that the Taihua complex with various gneisses and the degree of parting melting were the dominant two factors for the divergence of U and Th in the Huashan granite.
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Keywords:
- helium /
- granites /
- occurrence /
- restrict factor /
- Weihe basin
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柴先平. 西安地热水伴生富氦天然气成因研究[D]. 西安:长安大学, 2007. CHAI Xianping. Study to the formation of Nature gas enriched Helium in geothermal water in Xi'an District[D]. Xi'an:Chang'an University, 2007.
戴金星, 宋岩, 戴春森, 等. 中国东部无机成因气及其气藏形成条件[M].北京:科学出版社, 1995. 第五春荣, 刘祥, 孙勇. 华北克拉通南缘太华杂岩组成及演化[J]. 岩石学报, 2018, 34(4):999-1018. DIWU Chunrong, LIU Xiang, SUN Yong. The composition and evolution of the Taihua Complex in the southern North China Craton[J]. Acta Petrologica Sinica, 2018, 34(4):999-1018.
董敏, 王宗秀, 董会, 等. 关中盆地花岗岩石英脉流体包裹体与氦气成藏特征研究[J]. 西北地质, 2017, 50(3):222-230. DONG Min, WANG Zongxiu, DONG Hui, et al. Fluid inclusions characteristics of quartz vein in granite and helium accumulation in Guanzhong Basi, Shaanxi Province[J]. Northwestern Geology, 2017, 50(3):222-230.
董敏, 王宗秀, 董会, 等. 应用拉曼光谱和裂变径迹法对关中盆地氦气成藏特征的实验研究[J]. 科学技术与工程, 2018, 18(27):7-12. DONG Min, WANG Zongxiu, DONG Hui, et al. Experimental study on helium accumulation characteristics in Guanzhong Basin by Raman spectroscopy and fission track method[J]. Science Technology and Engineering, 2018, 18(27):7-12.
高龙刚, 陈佑纬, 毕献武, 等. 陕西华阳川铀铌矿床中铀矿物的年代学与矿物化学研究及其对铀成矿的启示[J]. 地质学报, 2019, 93(9):2273-2291. GAO Longgang, CHEN Youwei, BI Xianwu, et al. Chronology and mineral chemistry of the uranium minerals in Huayangchuan uranium-niobium deposit, Shaanxi Province and its implications for uranium mineralization[J]. Acta Geological Sinica, 2019, 93(9):2273-2291.
郭波, 朱赖民, 李犇, 等. 华北陆块南缘华山和合峪花岗岩岩体锆石U-Pb年龄、Hf同位素组成与成岩动力学背景[J]. 岩石学报, 2009, 25(2):265-281. GUO Bo, ZHU Laimin, LI Ben, et al.Zircon U-Pb age and Hf isotope composition of the Huashan and Heyu granite plutons at the southern margin of North China Craton:Implications for geodynamic setting[J]. Acta Petrologica Sinica, 2009, 25(2):265-281.
韩伟, 李玉宏, 卢进才, 等. 陕西渭河盆地富氦天然气异常的影响因素[J]. 地质通报, 2014, 33(11):1836-1841. HAN Wei, LI Yuhong, LU Jincai, et al. The factors responsible for the unusual content of helium-rich natural gas in the Weihe Basin, Shaanxi Province[J]. Geological Bulletin of China, 2014, 33(11):1836-1841.
黄建军, 周阳, 滕宏泉, 等. 关中盆地西安凹陷地热水赋存特征及其资源量估算[J]. 西北地质, 2021, 54(1):196-203. HUANG Jianjun, ZHOU Yang, TENG Hongquan, et al. On the occurrence characteristics and the estimation of geothermal water in Xi'an Sag, Guanzhongbasin[J]. Northwestern Geology, 2021, 54(1):196-203.
李玉宏, 卢进才, 李金超, 等. 渭河盆地富氦天然气井分布特征与氦气成因[J]. 吉林大学学报(地球科学版), 2011, 41(S1):47-53. LI Yuhong, LU Jincai, LI Jinchao, et al. Distribution of the Helium-Rich Wells and Helium Derivation in Weihe Basin[J]. Journal of Jilin University (Earth Science Edition), 2011, 41(S1):47-53.
李玉宏, 张文, 王利, 等. 亨利定律与壳源氦气弱源成藏——以渭河盆地为例[J]. 天然气地球科学, 2017, 28(4):495-501. LI Yuhong, ZHANG Wen, WANG Li, et al. Henry's law and accumulation of crust-derived helium:A case from Weihebasin, China[J]. Natural Gas Geoscience, 2017, 28(4):495-501.
李玉宏, 周俊林, 张文, 等. 渭河盆地氦气成藏条件及资源前景[M]. 北京:地质出版社, 2018, 1-289. 李争, 段奕. 阿尔及利亚三叠盆地成藏主控因素分析[J]. 天然气技术与经济, 2009, 3(5):10-13. LI Zheng, DUAN Yi. Main Reservoir-forming Controlling Factors of Triassic Basin, Algeria[J]. Natural Gas Technology, 2009, 3(5):10-13.
刘建朝, 李荣西, 魏刚峰, 等. 渭河盆地地热水水溶氦气成因与来源研究[J]. 地质科技情报, 2009, 28(6):84-88. LIU Jianchao, LI Rongxi, WEI Gangfeng, et al. Origin and Source of Soluble Helium Gas in Geothermal Water, Weihe Basin[J]. Geological Science and Technology Information, 2009, 28(6):84-88.
刘锐, 陈觅, 田向盛, 等. 东秦岭蓝田和牧护关岩体地球化学、锆石SIMS U-Pb年龄及Hf 同位素特征:岩石成因及构造意义[J]. 矿物学报, 2014, 34(4):469-480. LIU Rui, CHEN Mi, TIAN Xiangsheng, et al. Geochemical, Zircon SIMS U-Pb Geochronological and Hf Isotopic Study on Lantian and Muhuguan Plutons in Eastern Qinling, China:Petrogenesis and Tectonic Implications[J]. Acta Mineralogica Sinica, 2014, 34(4):469-480.
卢进才, 魏仙样, 李玉宏, 等. 汾渭盆地富氦天然气成因及成藏条件初探[J]. 西北地质, 2005, 38(3):82-86. LU Jincai, WEI Xianyang, LI Yuhong, et al. Preliminary study about genesis and pool formation conditions of rich-helium type natural gas[J]. Northwestern Geology, 2005, 38(3):82-86.
齐秋菊, 王晓霞, 柯昌辉, 等. 华北地块南缘老牛山杂岩体时代、成因及地质意义-锆石年龄、Hf同位素和地球化学新证据[J]. 岩石学报, 2012, 28(1):279-301. QI Qiuju, WANG Xiaoxia, KE Changhui, et al. Geochronology and origin of the Laoniushan complex in the southern margin of North China Block and their implications:New evidences from zircon dating, Hf isotopes and geochemistry[J]. Acta Petrologica Sinica, 2012, 28(1):279-301.
徐永昌, 沈平, 陶明信, 等. 东部油气区天然气中幔源挥发份的地球化学——I.氦资源的新类型:沉积壳层幔源氦的工业储集[J]. 中国科学(D辑), 1996, 26(1):1-8. XU Yongchang, SHEN Ping, TAO Mingxin, et al. Geochemistry of mantle-derived volatiles in natural gas from oil and gas regions, Eastern China:I A new type of helium:industrial storage of mantle-derived helium in sedimentary crust[J]. Science in China (Series D), 1996, 26(1):1-8.
薛华锋, 朱兴国, 王润三, 等. 西安地热田伴生富氦天然气资源的发现及意义[J]. 西北大学学报(自然科学版), 2004, 34(6):751-754. XUE Huafeng, ZHU Xingguo, WANG Runsan, et al. The discovery and significance of rich Helium natural gas resource in Xianl. Journal of Northwest University (Natural Science Edition), 2004, 34(6):751-754.
张福礼, 孙启邦, 王行运, 等. 渭河盆地水溶氦气资源评价[J]. 地质力学学报, 2012, 18(02):195-202. ZHANG Fuli, SUN Qibang, WANG Xingyun, et al. Evaluation ofwater soluble helium resources in Weihe basin. Journal of Geomechanics, 2012, 18(02):195-202.
张国伟, 张本仁, 袁学诚, 等. 秦岭造山带与大陆动力学[M]. 北京:科学出版社, 2001. 张文.关中和柴北缘地区战略性氦气资源成藏机理研究[D]. 北京:中国矿业大学(北京), 2019. ZHANG Wen. Accumulation mechanism of helium, a strategic resource, in Guanzhong and North Qaidam Basin[D].Beijing:China University of Mining & Technology-Beijing, 2019.
张文, 李玉宏, 王利, 等. 渭河盆地氦气成藏条件分析及资源量预测[J]. 天然气地球科学, 2018, 29(2):236-244. ZHANG Wen, LI Yuhong, WANG Li, et al.The analysis of helium accumalation conditions and prediction of helium resource in Weihe Basin[J]. Natural Gas Geoscience, 2018, 29(2):236-244.
张兴康, 叶会寿, 李正远, 等. 小秦岭华山复式岩基大夫峪岩体锆石U-Pb年龄、Hf同位素和地球化学特征[J]. 矿床地质, 2015, 34(02):235-260. ZHANG Xingkang, YE Huishou, LI Zhengyuan, et al. Zircon U-Pb ages, Hf isotopic composition and geochemistry of Dafuyu granitoid poluton from Huashan complex batholith in Xiaoqinling[J]. Mineral Deposits, 2015, 34(02):235-260.
张晓宝, 徐永昌, 孙明良, 等. 黄骅坳陷含油储层包裹体中幔源氦的发现及其地质意义[J]. 中国科学:地球科学, 2003, 33(07):673-678. ZHANG Xiaobao, XU Yongchang, SUN Mingliang, et al. Discovery of mantle-derived helium in inclusions from oil-bearing reservior in Huanghua Depression and its significance[J]. Science in China (Series D), 2003, 33(07):673-678.
张雪. 渭河盆地天然气及氦气成藏条件与资源量预测[D]. 西安, 长安大学, 2015, 102-119. ZHANG Xue. Accumulation conditions and resource prediction of natural gas and helium gas in Weihe basin[D]. Xi'an:Chang'an University, 2015, 102-119.
张宗清, 张国伟, 刘敦一, 等. 秦岭造山带蛇绿岩, 花岗岩和碎屑沉积岩同位素年代学和地球化学[M]. 北京:地质出版社, 2006. Ballentine C J, Dan N B. The origin of air-like noble gases in MORB and OIB[J]. Earth & Planetary Science Letters, 2000, 180(1-2):39-48.
Ballentine C J, Sherwood L B. Regional groundwater focusing of nitrogen and noble gases into the Hugoton-Panhandle giant gas field, USA[J]. Geochimica et Cosmochimica Acta, 2002, 66(14):2483-2497.
Brown A A. Formation of High Helium Gases:A Guide for Explorationists[C]. AAPG Convention, New Orleans, Louisiana, USA. 2010.
Cherniak D J, Watson E B, Thomas J B. Diffusion of helium in zircon and apatite[J]. Chemical Geology, 2009, 268(1-2):155-166.
Danabalan D, Gluyas J G, Macpherson G G, et al. New High-Grade Helium Discoveries in Tanzania[C]. Yokohama, Japan:Goldschmidt Conference. 2016.
Gao Shan, Luo Tingchuan, Zhang Benren, et al. Chemical composition of the continental crust as revealed by studies in east China[J]. Geochim. Cosmochim. Acta, 1998, 62:1959-1975.
Green T H. Experimental studies of trace-element partitioning applicable to igneous petrogenesis-Sedona 16 years later[J]. Chemical Geology, 1994, 117(1-4):1-36.
Hu Jian, Jiang Shaoyong, Zhao Haixiang, et al.Geochemistry and petrogenesis of the Huashan granites and their implications for the Mesozoic tectonic settings in the Xiaoqinling gold mineralization belt, NW China[J]. Journal of Asian Earth Sciences, 2012, 56:276-289.
Hussain N. Flux of 4He from Carnmenellis granite:modelling of an HDR geothermal reservoir[J]. Applied Geochemistry, 1997, 12(1):1-8.
Jia Xiaoliang, Zhai Mingguo, Xiao Wenjiao, et al. Late Neoarchean to early Paleoproterozoic tectonic evolution of the sourthern North China Craton:Evidence from geochemistry, zircon geochronology and Hf isotopes of felsic gneisses from the Taihua complex[J]. Precambrian Research, 2019, 326:222-239.
Jiang Shaoyong.Controls on the mobility of high field strength elements (HFSE), U, and Th in an ancient submarine hydrothermal system of the Proterozoic Sullivan Pb-Zn-Ag deposit, British Columbia, Canada[J]. 2000, Geochemical Journal, 34:341-348.
Kukkonen I T, and Lauri L S. Modelling the thermal evolution of a collisional Precambrian orogen:High heat production migmatitic granites of southern Finland[J]. Precambrian Research, 2009, 168(3-4):233-246.
Luhr J F, Carmichael I S E, Varekamp J C. The 1982 eruptions of El Chichón Volcano, Chiapas, Mexico:Mineralogy and petrology of the anhydritebearing pumices[J]. Journal of Volcanology and Geothermal Research, 1984, 23:69-108.
Luo Yan, Ayers J C. Experimental measurements of zircon/melt trace-element partition coefficients[J]. Geochimica Et Cosmochimica Acta, 2009, 73(12):3656-3679.
Martel D J, O'Nions R K, Hilton D R, et al. The role of element distribution in production and release of radiogenic helium:the Carnmenellis Granite, southwest England[J]. Chemical Geology, 1990, 88(3):207-221.
Nash W P. & Crecraft H R. Partition coefficients for trace elements in silicic magmas[J]. Geochimica et Cosmochimica Acta, 1985, 49:2309-2322.
Nuttall W J, Richard H, Clarke, et al. Resources:stop squandering helium[J]. Nature, 2012, 485(7400).
Robb L. Introduction to ore forming processes[M]. Blackwell Science Ltd, Oxford, 2005.
Rudnick R and Gao S. Composition of the continental crust[J]. The Crust, 2003, 3:1-64.
Shaw D M. Trace element fractionation during anatexis[J]. Geochimica et Cosmochimica Acta, 1970, 34:237-243.
Wang Xue, Huang Xiaolong, Yang Fan. Geochronology and geochemistry of the Xiaoqinling Taihua Complex in the southern Trans-North China Orogen:Implications for magmatism during the early Paleoproterozoic global tectono-magmatic shutdown[J]. Lithos, 2021:402-403.
Xue Yingyu, Siebel W, He Jianfeng, et al. Granitiod Petrogenesis and Tectonic Implications of the Late Triassic Baoji Pluton, North Qinling Orogen, China:Zircon U-Pb Ages and Geochemical and Sr-Nd-Pb-Hf Isotopic Compositions[J]. The Journal of Geology, 2018, 126(1):119-139.
Zhang Jian, Yang Wei, Yi Haiyong, et al. Feasibility of high-helium natural gas exploration in the Presinian strata, the Sichuan Basin[J]. Natural Gas Industry B, 2015, 2(1):88-94.
Zhang Wen, Li Yuhong, Zhao Fenghua, et al. Granite is an Effective Helium Source Rock:Insights from the Helium Generation and Release Characteristics in Granites from the North Qinling Orogen, China[J]. Acta Geologica Sinica (English edition), 2020, 94(1):114-125.
Zheng Hui, Chen Huayong, Wu Chao, et al. Genesis of the supergiant Huayangchuan carbonatite-hosted uranium-polymetallic deposit in the Qinling Orogen, Central China[J]. Gondwana Research, 2020, 86:250-265.
Zhu Mingtian, Zhang Lianchang, Wu Guan, et al. Fluid inclusions and He-Ar isotopes in pyrite from the Yinjiagou deposit in the southern margin of the North China Craton:A mantle connection for poly-metallic mineralization[J]. Chemical Geology, 2013, 351:1-14.
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